FIELD: industrial organic synthesis.
SUBSTANCE: invention provides a process for production of alkylene glycols, which are useful as components for low-freezing, antiicing, hydraulic, and braking fluids as well as in production of solvents, plasticizers, for obtaining materials used in plastic industry, pesticides, lacquers, and paints. Process comprises hydration of alkylene oxide at elevated temperatures and pressure in displacement reactor in presence of catalytic system based on anion-exchange resins in salt form and organic or inorganic iodine compounds.
EFFECT: reduced catalyst swelling rate and increased selectivity of process.
2 tbl, 7 ex
| Title | Year | Author | Number |
|---|---|---|---|
| PROCESS OF PRODUCING ALKYLENE GLYCOLS | 2004 |
|
RU2284985C2 |
| METHOD OF REGENERATING BASIC ANIONITE CATALYSTS | 2006 |
|
RU2322295C1 |
| METHOD OF SYNTHESIS OF ALKYLENE GLYCOLS | 1999 |
|
RU2149864C1 |
| METHOD OF PREPARING ALKYLENE GLYCOLS | 1997 |
|
RU2122995C1 |
| METHOD FOR PREPARING ALKYLENE GLYCOLS | 1998 |
|
RU2211211C2 |
| SOLID CATALYST USED TO CONVERT ALKYLENE OXIDE TO ALKYLENE GLYCOL | 2008 |
|
RU2470706C2 |
| METHOD FOR PREPARING ALKYLENE GLYCOLS | 1999 |
|
RU2222522C2 |
| METHOD OF PRODUCING ALKYLENE GLYCOL | 2008 |
|
RU2467996C2 |
| CATALYTIC HYDROLYSIS OF ALKYLENE OXIDES | 1998 |
|
RU2203879C2 |
| METHOD FOR CATALYZED PRODUCTION OF ALKYLENE GLYCOL WITH RECYCLE OF REACTION PRODUCT | 2001 |
|
RU2267478C2 |
