FIELD: organic chemistry, chemical technology, polymers.
SUBSTANCE: invention relates to novel polyalkoxylated trimethylolpropane (meth)acrylic esters. Invention proposes polyesters of the following formulas (Ib) and (Ic) wherein EO means O-CH2-CH2-; PO means independently of one another O-CH2-CH(CH3)- or O-CH(CH3)-CH2-; n1 + n2 + n3 = 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 54, 55, 56, 57, 58, 59 or 60; m1 + m2 + m3 = 4, 5, 6, 7, 8, 9, 10, 11, 12 or 13; R1, R2 and R3 mean independently of one another hydrogen atom (H) or -CH3. Proposed esters can be used in preparing polymers absorbing aqueous liquids and forming hydrogel. Invention provides development of compounds that can be used as radical cross-linking agent, in particular, for superabsorbers.
EFFECT: valuable properties of esters.
12 cl, 2 tbl, 7 ex
Title | Year | Author | Number |
---|---|---|---|
POLYMERS PRODUCING HYDROGEL AND ABSORBING AQUEOUS LIQUIDS, PRODUCTION METHOD AND APPLICATION OF MONOETHYLENOID-NONSATURATED C-C-CARBOXYLIC ACIDS CONTAINING α-TOCOPHEROL AS STABILISING ADDITIVE | 2002 |
|
RU2329066C9 |
SUPERABSORBENT POLYMERS CAPABLE OF FAST ABSORPTION AND SYNTHESIS METHOD THEREOF | 2012 |
|
RU2586214C2 |
METHOD OF PRODUCING CARBOXYLIC ACID DERIVATIVES | 2007 |
|
RU2448949C2 |
MIXTURES CONTAINING OLIGOMERIC OR POLYMERIC COMPOUNDS, PRODUCTION AND USE THEREOF | 2010 |
|
RU2541564C9 |
POWDER-LIKE POLYMERS ABSORBING AQUEOUS LIQUIDS, METHOD OF THEIR SYNTHESIS | 1994 |
|
RU2125468C1 |
HYDROXYPHENYLTRIAZINES CONTAINING AROMATIC CARBOCYCLIC CONDENSED RING SYSTEM | 2006 |
|
RU2418791C2 |
METHOD FOR OBTAINING THE MODIFIED EPOXIES OF (METH) ACRYLATE RESINS AND THEIR APPLICATION | 2013 |
|
RU2648042C2 |
INORGANIC BINDER COMPOSITION COMPRISING COPOLYMER | 2015 |
|
RU2701654C2 |
ENZYMATIC PRODUCTION OF (METH)ACRYLIC ESTERS | 2006 |
|
RU2431673C2 |
COMPOSITION OF THERMALLY SOLIDIFIED POWDER COATING | 2009 |
|
RU2521039C2 |
Authors
Dates
2008-03-27—Published
2003-06-06—Filed