FIELD: production of optical laser materials used as optical medium for transmitting, generating, and converting photon radiation at optical-signal different frequency and power.
SUBSTANCE: source mixture of metal fluorides has base in the form of one or more fluorides out of group of alkali-earth metals and alloy additive; the latter and base are capable of producing homogenous solid solution of fluorite structure at molar proportion of 50-90/50-1; source mixture has components with fluorine-ion excess introduced therein. Proposed laser fluoride ceramic production process includes hot pressing of source mixture of crushed fluoride fractures of alkali-earth and rare-earth metals using active fluorinating agent. Fluorinating agents are obtained by their gaseous liberation during decomposition of source components under pre-evacuation and heating conditions. Source mixture used for the purpose incorporates mentioned composition. Hot pressing is conducted at temperature of minimum 900 °C. Additional fluorination of charge is conducted by means of gaseous CF4 supplied from outside.
EFFECT: ability of producing highly transparent laser material suited to transfer, generate, and convert photon radiation at different frequencies and power of optical signals, including those unattainable for monocrystals.
5 cl, 1 tbl
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METHOD OF PRODUCING GLASS CERAMICS WITH NANOSIZED CRYSTALS OF SOLID SOLUTIONS TITANATES-ZIRCONATES OF ERBIUM AND/OR YTTERBIUM | 2015 |
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Authors
Dates
2008-03-27—Published
2006-10-02—Filed