CATALYST, METHOD FOR PREPARATION THEREOF, AND A PROCESS OF DEHYDROGENATION OF C-C-PARAFFIN HYDROCARBONS INTO OLEFINS Russian patent published in 2008 - IPC B01J23/26 B01J23/10 B01J23/04 B01J21/02 B01J35/02 B01J37/02 C07C5/333 B82B1/00 

Abstract RU 2322290 C1

FIELD: petrochemical processes and catalysts.

SUBSTANCE: invention relates to the area of production of olefin hydrocarbons via catalytic dehydrogenation of corresponding C3-C5-paraffin hydrocarbons and can be applied in chemical and petrochemical industries. C3-C5-Paraffin hydrocarbon dehydrogenation catalyst is described containing chromium oxide, alkaline metal oxide, transition metals, and carrier, said carrier being nanostructured oxygen-containing aluminum compound of general formula: Al2O3-x(OH)x*nH2O, wherein x=0-0.28 and n=0.03-1.8, consisting of nanostructured primary particles 2-5 nm in size and characterized by disordered/imperfect layered structure similar to byerlyte structure. Method of preparing this catalyst as well as process of dehydrogenating C3-C5-paraffin hydrocarbons into olefins are also described, the latter being conducted in fluidized bed of described catalyst, which is recycled within the circuit: dehydrogenation reactor - regeneration reactor.

EFFECT: increased mechanical strength at high catalytic activity and stability.

20 cl, 1 dwg, 2 tbl, 10 ex

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RU 2 322 290 C1

Authors

Molchanov Viktor Viktorovich

Pakhomov Nikolaj Aleksandrovich

Isupova Ljubov' Aleksandrovna

Balashov Vladimir Aleksandrovich

Kharina Irina Valer'Evna

Kashkin Vitalij Nikolaevich

Parakhin Oleg Afanas'Evich

Chernov Mikhail Pavlovich

Pecherichenko Vladimir Alekseevich

Aleksandrov Aleksandr Viktorovich

Pestov Vitalij Valentinovich

Dates

2008-04-20Published

2006-12-18Filed