FIELD: gas treatment catalysts.
SUBSTANCE: invention relates to a method for preparing catalyst and to catalyst supported by block ceramic and metallic carrier having honeycomb structure for treating internal combustion engine exhaust gases. Preparation of catalyst comprises preliminary calcination of inert honeycomb block carrier followed by simultaneously depositing at 550-800°C, on its surface, intermediate coating of modified alumina and active phase consisting of one or several platinum group metals from water-alcohol suspension including aluminum hydroxide (boehmite, AlOOH), cerium nitrate, and one or several inorganic salts of platinum group metals. Coated material is then dried and subjected to heat treatment and reduction. According to invention, aforesaid suspension contains boehmite and cerium nitrate at 1:2 ratio and further contains reducing disaccharide so that suspension has following composition, wt %: AlOOH 18-20, Ce(NO3)3·6H2O 36-40, one or several platinum group metal salts (e.g., H2PtCl6, PdCl3, or RhCl3 calculated as metals) 1.5-1.8, reducing disaccharide 5-6, and water/alcohol (between 5:1 and 10:1) the rest. Thus obtained catalyst for treating internal combustion engine exhaust gases is characterized by: specific surface area of coating 80-100 m2/g, Al2O3 content 2.5-6.5%, CeO2 content 2.5-6.5%, active phase (calculated for platinum group metals) 0.2-0.4%, and block carrier to 100%.
EFFECT: simplified technology due to reduced number of technological stages and shortened process time, and enabled preparation of high-activity catalyst.
6 cl, 1 tbl, 8 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PREPARING CATALYST FOR TREATING INTERNAL COMBUSTION ENGINE EXHAUST GASES AND CATALYST PREPARED BY THIS METHOD | 2004 |
|
RU2275962C1 |
METHOD OF PREPARING CATALYST FOR PURIFICATION OF EXHAUST GASES OF COMBUSTION ENGINES AND CATALYST OBTAINED THEREOF | 2012 |
|
RU2502561C1 |
PROCESS FOR MANUFACTURING CATALYST FOR PURIFICATION OF EXHAUST GASES | 1992 |
|
RU2005538C1 |
METHOD OF PREPARING CATALYST AND CATALYST FOR TREATING INTERNAL COMBUSTION ENGINE EXHAUST GASES | 2000 |
|
RU2169614C1 |
METHOD OF CATALYST PREPARATION AND CATALYST FOR EXHAUST GAS TREATMENT IN INTERNAL COMBUSTION ENGINES | 2007 |
|
RU2348457C2 |
METHOD OF PREPARING CATALYST AND CATALYST FOR OXIDISING AND CLEANING GASES | 2011 |
|
RU2470708C2 |
METHOD OF PREPARING CATALYST AND CATALYST FOR OXIDISING CO | 2015 |
|
RU2614147C1 |
CATALYST PREPARATION METHOD AND HYDROGEN OXIDATION CATALYST FOR APPARATUS FOR PASSIVE RECOMBINATION THEREOF | 2011 |
|
RU2486957C1 |
METHOD OF PREPARATION OF PURIFICATION CATALYSTS OF INTERNAL COMBUSTION ENGINES EXHAUST GASES | 2010 |
|
RU2442651C1 |
METHOD OF PREPARING CATALYST FOR CLEANING WASTES GASES OF INTERNAL COMBUSTION ENGINES | 2000 |
|
RU2190470C2 |
Authors
Dates
2008-04-20—Published
2006-12-04—Filed