FIELD: chemistry.
SUBSTANCE: invention refers to production of proton-conducting membranes based on ionogenic hydrophilic copolymers applied in membrane fuel elements. According to invention polymer composition for proton-conducting membranes designed as interpenetrating polymer networks composed of N-vynilpyrrolidone ionogenic copolymer network, acrylonitrile, 2-acrylamide-2-methyl-1-propanesulphacid and cross-linking monomer (ethyleneglycoldimethacrylate or methylenebisacrylamide) at mass monomers relation (34.5-46.5):(34.5-46.5):(16.5-20.0):(0.5-2.0) and N-vynilpyrrolidone ionogenic copolymer network, acrylonitrile and ethyleneglycoldimethacrylate at mass monomers relation (19.5-79.5):(19.5-79.5):(1.0-2.0). Mass copolymer relation is within the range 1.3-6.76. Polymer composition production includes sequential stages: synthesis of cross-linked ionogenic copolymer by means of radical copolymerization of specified monomers in divided closed polymer mold; saturation of crossed-linked ionogenic copolymer with monomers forming non-ionogenic copolymer network, radical copolymerization of monomers and formation of interpenetrating polymer networks.
EFFECT: production of polymer material for membranes high-conductivity and mechanical strength.
12 cl, 2 tbl, 16 ex
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Authors
Dates
2008-05-27—Published
2007-04-13—Filed