FIELD: chemistry.
SUBSTANCE: invention pertains to the method of methanol obtaining from a concentrated mixture of hydrogen and carbon oxides with the following components in vol %: H2 - 62.0-78.5; Ar - 0.02-0.07; N2 - 0.05-2.2; CH4 - 1.0-3.5; CO - 10.4-29.5; CO2 - 3.2-10.7. The methanol is obtained by concentrating it in a copper containing catalyst at high temperature and pressure in two stages. The gas mixture from the reformer is divided into two streams in volume ratios of 100 : (1-50), one of which is in direct contact with the catalyst in the flow reactor at the first stage, at temperature of 200-285°C, pressure of 5-15 MPa and volume rate of 800-2000 h-1. The other stream is mixed with a cycled gas in volume ratio of 10 : (10-100) and with volume rate of 2500-10000 h-1. This stream is then channelled to the second stage, with separation of methanol and water on each stage in corresponding devices.
EFFECT: increased production of methanol and increased efficiency of the process.
1 tbl, 1 dwg
Title | Year | Author | Number |
---|---|---|---|
METHOD OF METHANOL OBTAINING | 2006 |
|
RU2331625C2 |
METHANOL SYNTHESIS METHOD | 2018 |
|
RU2698200C1 |
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METHANOL PRODUCTION PROCESS | 2006 |
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METHOD OF PRODUCTION OF HYDROGEN AND METHANOL | 2004 |
|
RU2285660C2 |
METHOD OF COMBINED PREPARATION OF AMMONIA AND METHANOL | 2000 |
|
RU2174953C1 |
METHOD OF METHANOL PRODUCTION | 0 |
|
SU1799865A1 |
PROCESSING OF NATURAL GAS TO PRODUCE METHANOL | 1998 |
|
RU2135454C1 |
METHOD OF SYNTHESIS OF METHANOL | 1999 |
|
RU2181117C2 |
METHOD OF PREPARING METHANOL | 1997 |
|
RU2117627C1 |
Authors
Dates
2008-08-20—Published
2007-04-11—Filed