FIELD: chemistry.
SUBSTANCE: present invention relates to the organic synthesis, specifically to the method of obtaining a new organoaluminium - 1-ethyl-1,2,3,3a,4,5,6,7,8,9-decahydrocyclone[b]aluminacyclopentane. The specified compound can find application as a component in the catalyst system in processes of oligo- and olefinic polymerisation, diene and acetylene hydrocarbons, and also in delicate organic and metallo-organic synthesis. The method consists in the combination of 1,2-nonadiene with triethyl aluminium in the presence of the catalyst zirconacenedichloride in an atmosphere of argon at room temperature in hexane for 8-12 hours.
EFFECT: obtaining compounds, which can find application as a component in the catalyst system in processes of oligo- and olefinic polymerisation, diene and acetylene hydrocarbons, and also in delicate organic and metallo-organic synthesis.
1 cl, 1 ex, 1 tbl
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF OBTAINING 1,2,3,3a,4,5,6,7,8,9-DECAHYDROCYCLONONE[b]-MAGNESACYCLOPENTANE | 2007 |
|
RU2342390C1 |
| METHOD OF PRODUCING 11-CHLORO-11-ALUMINA-TRICYCLO [10.7.0.0]NONADECA-9,12-DIENE | 2007 |
|
RU2349595C1 |
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|
RU2342395C2 |
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|
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| METHOD OF (9-ETHYL-1-CYCLONONENYL)MAGNESIUM HALOGENIDE OBTAINMENT | 2007 |
|
RU2355696C2 |
| exo-PENTACYCLO[5.4.0.0.0.0]UNDECANE-4-SPIRO-1'-(3'-ETHYL-3'-ALUMINIUM)CYCLOPENTANE SYNTHESIS METHOD | 2008 |
|
RU2404187C2 |
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|
RU2381230C2 |
| METHOD FOR PREPARING 2,6-DIETHYL-5,7-DIPHENYL-1,2,3,3a,4,6,8,8a-OCTAHYDROALUMACYCLOPENTADIENO[3,4-f]-ISOALUMAINDOLE | 2004 |
|
RU2280037C2 |
| METHOD OF COMBINED PRODUCTION OF TETRACYCLO [5.4.1.0.0]DODEC-3-ENE-9-SPIRO(3'-ETHYL-3'-ALUMINACYCLOPENTANE) AND TETRACYCLO [5.4.1.0.0]DODEC-4-ENE-9-SPIRO(3'-ETHYL-3'-ALUMINACYCLOPENTANE) | 2008 |
|
RU2376311C2 |
| METHOD OF PRODUCING EXO-TRICYCLO[4,2,1,0 ]NON-3-ANE-SPIRO-1'-(3'-ETHYL-3'-ALUMINIUM)CYCLOPENTANE | 2009 |
|
RU2420531C2 |
