FIELD: chemistry.
SUBSTANCE: invention relates to a method for synthesis of exo-pentacyclo[5.4.0.02.9.03.6.08.10]undecane-4-spiro-1'-(3'-ethyl-3'-aluminium)-cyclopentane of general formula 
. The method involves reaction of 4-methylene-exo-pentacyclo[5.4.0.02.9.03.6.08.10]undecane with triethylaluminium (Et3Al) in the presence of a zirconocene dichloride (Cp2ZrCl2) catalyst in molar ratio 4-methylene-exo-pentacyclo[5.4.0.02.9.03.6.08.10]undecane: Et3Al:Cp2ZrC2=10:(10-14):(0.6-1.0) in an argon atmosphere at normal pressure in hexane for 5-7 hours.
EFFECT: invention enables to obtain said compound which can be used as a component a catalyst system in oligo- and polymerisation of olefin, diene and acetylene hydrocarbons.
1 ex, 1 tbl
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING EXO-TRICYCLO[4,2,1,0 ]NON-3-ANE-SPIRO-1'-(3'-ETHYL-3'-ALUMINIUM)CYCLOPENTANE | 2009 |
|
RU2420531C2 |
| METHOD FOR SYNTHESIS OF endo-, exo-TETRACYCLO[4.5.1.0.0]DODEC-3(4)-ENE-9-SPIRO-1'-(3'-SELENIUM)CYCLOPENTANES | 2008 |
|
RU2404177C2 |
| METHOD OF PRODUCING exo-TRICYCLO[4,2,1,0]NONANE-3-SPIRO-1'-(3'-SELENIUM)CYCLOPENTANE | 2008 |
|
RU2408599C2 |
| METHOD OF PRODUCING TRICYCLO[4.2.1.0]NONANE-3-SPIRO (3'-ETHYL-3'-ALUMINACYCLOPENTANE) | 2008 |
|
RU2381230C2 |
| METHOD OF PRODUCING exo-TRICYCLO[4,2,1,0]NONANE-3-SPIRO-1'-(3'-THIA)CYCLOPENTANE | 2008 |
|
RU2408590C2 |
| METHOD OF COMBINED PRODUCTION OF TETRACYCLO [5.4.1.0.0]DODEC-3-ENE-9-SPIRO(3'-ETHYL-3'-ALUMINACYCLOPENTANE) AND TETRACYCLO [5.4.1.0.0]DODEC-4-ENE-9-SPIRO(3'-ETHYL-3'-ALUMINACYCLOPENTANE) | 2008 |
|
RU2376311C2 |
| METHOD OF PRODUCING 3-ETHYL-3-ALUMINATETRACYCLO[12.2.1.0.0]HEPTADEC-4-ENE | 2008 |
|
RU2375367C2 |
| METHOD OF 6-ETHYL-6-ALUMINASPIRO[3,4] OCTANE | 2007 |
|
RU2342392C2 |
| METHOD OF OBTAINING 1-ETHYL-1,2,3,3a,4,5,6,7,8,9-DECAHYDROCYCLONONE[b]ALUMINACYCLOPENTANE | 2007 |
|
RU2342393C2 |
| METHOD OF PRODUCING TRICYCLO[4,2,1,0]-NONANE-3-SPIRO-1'-BUTANE | 2008 |
|
RU2373174C1 |
