FIELD: chemistry.
SUBSTANCE: invention concerns organic synthesis, particularly method of obtaining new organic magnesium compounds, namely (9-ethyl-1-cyclononenyl)magnesium halogenides. Method involves reaction of 1,2-hohadiene with ethylmagnesium halogenide in the presence of zirconocene dichloride catalyst in argon atmosphere at room temperature in tetrahydrofurane for 6-10 hours.
EFFECT: application as catalytic system component in oligomerisation and polymerisation processes for olefin, diene and acetylene hydrocarbons, and in fine organic synthesis.
1 cl, 1 ex, 1 tbl
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF OBTAINING 1,2,3,3a,4,5,6,7,8,9-DECAHYDROCYCLONONE[b]-MAGNESACYCLOPENTANE | 2007 |
|
RU2342390C1 |
| METHOD OF OBTAINING 1-ETHYL-1,2,3,3a,4,5,6,7,8,9-DECAHYDROCYCLONONE[b]ALUMINACYCLOPENTANE | 2007 |
|
RU2342393C2 |
| METHOD OF PRODUCING 11-CHLORO-11-ALUMINA-TRICYCLO [10.7.0.0]NONADECA-9,12-DIENE | 2007 |
|
RU2349595C1 |
| METHOD OF PRODUCING 11-MAGNESATRICYCLO[10.7.0.0]NONADECA-9,12-DIENE | 2008 |
|
RU2375364C2 |
| METHOD OF PRODUCING 11,12-DIALKYL-10-MAGNESABICYCLO[7.3.0]DODECA-8,11-DIENES | 2007 |
|
RU2349594C1 |
| METHOD OF PRODUCING 3-ETHYL-3-ALUMINATETRACYCLO[12.2.1.0.0]HEPTADEC-4-ENE | 2008 |
|
RU2375367C2 |
| METHOD OF OBTAINING 10,11-DIALKYL-9-MAGNESABICYCLO[6,3,0]UNDECA-1(8),10-DIENES | 2007 |
|
RU2355695C2 |
| METHOD OF PRODUCING 10-ALKYL-12-ETHYL-12-ALUMINABICYCLO[7.3.0]DODEC-1( 2 )-ENES | 2008 |
|
RU2375368C2 |
| 3,4,5,6,7,8,9,10-OCTAHYDRO-2H-CYCLONONE[b]THIOPHENE SYNTHESIS METHOD | 2008 |
|
RU2401834C2 |
| METHOD OF OBTAINING 10-ETHYL-11,12-DIALKYL-10-ALUMINABICYCLO [7,3,0]DODECA-8,11-DIENES | 2007 |
|
RU2348640C1 |
