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2 355 672

(13)

(51)

IPC

C07C9/00(2006-01-01)

B01J31/22(2006-01-01)

(21) (22)

Application

2007139377/04, 2007-10-23

(24)

Start date

2007-10-23

(22)

Actual filing date

2007-10-23

(45)

Published

2009-05-20

(72)

Inventor

Bulgakov Ramil' GarifovichKaramzina Diana SergeevnaKuleshov Sergej PavlovichDzhemilev Usein Memetovich

(73)

Holder

Institut Neftekhimii I Kataliza Rossijskoj Akademii Nauk

METHOD OF CATALYTIC TRANSFORMATION OF CYCLIC HYDROCARBONS INTO ACYCLIC (LINEAR) HYDROCARBONS UNDER ACTION OF LANTHANIDES COMPLEXES Russian patent published in 2009 - IPC C07C9/00 B01J31/22

Abstract RU 2355672 C1

FIELD: chemistry.

SUBSTANCE: invention refers to the methods of linear hydrocarbons obtaining, specifically to the method of n-alkanes obtaining. The essence of the method lies in cycloalkanes hydrogenolyse in presence of the catalysts - complexes of lanthanides chlorides crystallohydrates with aluminium alkoxyde LnCl₃·3H₂O·3(EtO)₂AlOH in combination with i-Bu₂AlH in dioxane medium at atmospheric pressure and 80°C during 6 hrs.

EFFECT: increasing of the target product yield.

1 cl, 1 tbl, 6 ex

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RU 2 355 672 C1

Authors

Bulgakov Ramil' Garifovich

Karamzina Diana Sergeevna

Kuleshov Sergej Pavlovich

Dzhemilev Usein Memetovich

Dates

2009-05-20—Published

2007-10-23—Filed