METHOD FOR PRODUCTION OF QUINOLINE ALKYL-DERIVATIVES Russian patent published in 2006 - IPC C07D215/04 B01J27/10 

Abstract RU 2283837 C1

FIELD: organic chemistry.

SUBSTANCE: invention relates to method for production of derivatives of general formula , wherein R is C2H5, C3H7, C4H9. Claimed method includes reaction of aniline with aliphatic aldehydes in presence of catalyst. Method is characterized in that as catalyst crystallohydrate of lanthanide trichloride (LnCl3.6H2O, Ln = Pr, Nd, Eu) and triisobutylaluminum (iso-Bu3Al)in LnCl3.6H2O:(iso-Bu3Al) molar ratio of 1:12 are used. Process is carried out in air, under atmospheric pressure and room temperature in toluene for 25 min. quinoline and derivatives thereof are useful in synthesis of cyan dyes, as extractants, sorbents and corrosion inhibitors.

EFFECT: simplified method with increased yield.

1 cl, 1 tbl, 7 ex

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RU 2 283 837 C1

Authors

Bulgakov Ramil' Garifovich

Kuleshov Sergej Pavlovich

Makhmutov Ajnur Rashitovich

Vafin Ruslan Radikovich

Karamzina Diana Sergeevna

Dzhemilev Usein Memetovich

Dates

2006-09-20Published

2005-05-13Filed