FIELD: chemistry.
SUBSTANCE: invention relates to organic synthesis, specifically to a method of producing new organoaluminium compounds which can be used as components of catalyst systems in oligo- and polymerisation processes of olefin, diene and acetylene hydrocarbons, as well as in fine organic and organometallic synthesis. A method is described for producing 11-magnesatricyclo[10.7.01.12.02.10]nonadeca-9,12-diene of general formula (I), which involves reacting 1,2-cyclononadiene with ethylmagnesium bromide in the presence of magnesium (powder) and a titanocene dichloride catalyst in an argon atmosphere at room temperature in diethyl ether for 8 to 12 hours.
EFFECT: proposed method allows for obtaining a new compound with high regioselectivity and high output 74-89%.
1 cl, 1 tbl, 9 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING 11-CHLORO-11-ALUMINA-TRICYCLO [10.7.0.0]NONADECA-9,12-DIENE | 2007 |
|
RU2349595C1 |
| METHOD OF (9-ETHYL-1-CYCLONONENYL)MAGNESIUM HALOGENIDE OBTAINMENT | 2007 |
|
RU2355696C2 |
| METHOD OF OBTAINING 1,2,3,3a,4,5,6,7,8,9-DECAHYDROCYCLONONE[b]-MAGNESACYCLOPENTANE | 2007 |
|
RU2342390C1 |
| METHOD OF PRODUCING 3-ETHYL-3-ALUMINATETRACYCLO[12.2.1.0.0]HEPTADEC-4-ENE | 2008 |
|
RU2375367C2 |
| 1,2,3,4,5,6,10,11,12,13,14,15,15a,15b-TETRADECAHYDRO-DICYCLONONE[b,d]THIOPHENE SYNTHESIS METHOD | 2008 |
|
RU2398772C2 |
| METHOD OF PRODUCING 1,2,3,4,5,6,7,9,10,11,12,13,14,15-TETRADECAHYDRODICYCLONONE[b,d]THIOPHENE | 2008 |
|
RU2382775C1 |
| 1, 2, 3, 4, 5, 6, 10, 11, 12, 13, 14, 15, 15a, 15b-TETRADECAHYDRODICYCLONONE[b,d]SELENOPHENE SYNTHESIS METHOD | 2008 |
|
RU2401835C2 |
| METHOD OF PRODUCING 3-ALKYLIDENE-4-MAGNESABICYCLO[7.3.0]DODEC-5-ENES | 2008 |
|
RU2375365C2 |
| METHOD OF PRODUCING 2-ALKYL-5,6,7,8,9,10-HEXAHYDRO-4H-CYCLONONE [b]THIOPHENES | 2008 |
|
RU2382776C1 |
| METHOD OF OBTAINING 1-ETHYL-1,2,3,3a,4,5,6,7,8,9-DECAHYDROCYCLONONE[b]ALUMINACYCLOPENTANE | 2007 |
|
RU2342393C2 |
