FIELD: chemistry.
SUBSTANCE: description is given of use of a catalyst system for (co)oligomerisation of lactide or glycolide with ring opening. The catalyst system is formed by a polymer catalyst based on a strongly acidic ion-exchange resin (1) and a (co)oligomerisation additive of formula (2) R1-E-R2, in which E is an element of the 16th group, R1 is a hydrogen or deuterium atom, R2 is a hydrogen or deuterium atom or a group in formula - E14(R14)(R'14)(R"14), where E14 is an element of the 14th group, R14, R'14, R"14 - represent a hydrogen atom, a deuterium atom, substituted or unsubstituted alkyl, cycloalkyl or aryl.
EFFECT: proposed catalyst system allows for controlling chain length and nature of terminal groups of compounds, separate compounds from a catalyst using a simple and efficient method and prevent loss of catalyst activity.
14 cl, 8 ex
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Authors
Dates
2010-01-27—Published
2005-03-15—Filed