CATALYST AND METHOD OF OXIDATIVE DEMECAPTANISATION OF OIL AND OIL PRODUCTS Russian patent published in 2010 - IPC B01J23/745 B01J23/75 B01J21/18 C10G27/10 C09B47/00 

Abstract RU 2381065 C1

FIELD: chemistry.

SUBSTANCE: catalyst for oxidative demercaptanisation of oil and oil products is described, where the said catalyst is phthalocyanine deposited activated carbon and is distinguished by that, it contains charged phthalocyanine with structural formula I or its supramolecular ion-associates with oppositely charged phthalocyanine with structural formula I, I:(R+)nPcM, where R=-CH2N+(CH3)2CH2CH2OHCl- (choln- PcM), n=2÷8, M=Co, Fe; (pymn-PcM), n=2÷8, M=Co, Fe; (R-)nPcM, where R=-CH2P(=O)(O-Na+)2(phosn-PcM), n=8, M-Co or II, II:(R-)nPcM, where R=R1=R2=-C(O)O-Na+ (carb8-PcM), n=8, M=Co, Fe; R=R1=-C(O)O-Na+, R2=H (carb4-PcM), n=4, M=Co; R= R1=-S(O)2O-Na+ , R2=H (sul4-PcM), n=4, M=Co. Also described is a method of oxidative catalytic demercaptanisation of oil and oil products with atmospheric oxygen at room temperature in the presence of the above described catalyst.

EFFECT: carrying out the process in mild conditions with complete substrate conversion.

4 cl, 2 tbl, 59 ex

Similar patents RU2381065C1

Title Year Author Number
CATALYST AND METHOD OF HOMOGENEOUS OXIDATIVE DEMERCAPTANISATION OF OIL AND OIL PRODUCTS 2008
  • Vorozhtsov Georgij Nikolaevich
  • Egorova Ol'Ga Jur'Evna
  • Kalija Oleg Leonidovich
  • Kravchuk Ol'Ga Vital'Evna
  • Luk'Janets Evgenij Antonovich
  • Negrimovskij Vladimir Mikhajlovich
  • Petrova Ekaterina Grigor'Evna
  • Solov'Eva Ljudmila Ivanovna
  • Juzhakova Ol'Ga Alekseevna
RU2381067C1
CATALYST AND METHOD OF OXIDISING SODIUM SULPHIDE 2008
  • Vorozhtsov Georgij Nikolaevich
  • Egorova Ol'Ga Jur'Evna
  • Kalija Oleg Leonidovich
  • Luk'Janets Evgenij Antonovich
  • Negrimovskij Vladimir Mikhajlovich
  • Petrova Ekaterina Grigor'Evna
  • Solov'Eva Ljudmila Ivanovna
  • Juzhakova Ol'Ga Alekseevna
RU2381066C1
METHOD OF PRODUCING HIGH-MODULUS FIBRE FROM AVERAGE-STRENGTH CARBON FIBRE 2008
  • Balakhonov Jurij Andreevich
  • Podkopaev Sergej Aleksandrovich
  • Stepanenko Aleksej Anatol'Evich
  • Vinogradov Oleg Vladimirovich
RU2400577C2
SUBSTITUTED IRON PHTHALOCYANINES AND METHOD OF OBTAINING CHLOR-DERIVATIVES OF AROMATIC HYDROCARBONS 2007
  • Kalija Oleg Leonidovich
  • Fedorova Tat'Jana Mikhajlovna
  • Vorozhtsov Georgij Nikolaevich
  • Egorova Tat'Jana Ivanovna
  • Kutsel' Tat'Jana Kuz'Minichna
  • Luk'Janets Evgenij Antonovich
  • Negrimovskij Vladimir Mikhajlovich
  • Petrova Ekaterina Grigor'Evna
  • Juzhakova Ol'Ga Alekseevna
RU2340589C1
METHOD FOR PRODUCING A CATALYST COMPOSITION FOR DEMERCAPTANISATION OF OIL AND OIL PRODUCTS 2015
  • Shelyapin Oleg Pavlovich
  • Voronin Evgenij Konstantinovich
  • Voronin Aleksandr Evgenevich
  • Akhtyamov Oskar Zufarovich
  • Shchelyvanov Evgenij Yurevich
  • Mazgarov Akhmet Mazgarovich
  • Vildanov Azat Faridovich
  • Aslyamov Ildar Ravilevich
  • Korobkov Fedor Aleksandrovich
  • Borovkov Aleksandr Grigorevich
  • Kultaev Aleksandr Valentinovich
RU2600318C1
CATALYST AND METHOD FOR VALENCE ISOMERISATION OF QUADRICYCLANE IN NORBORNADIENE 2011
  • Kuznetsova Nina Aleksandrovna
  • Kalija Oleg Leonidovich
  • Leont'Eva Svetlana Viktorovna
  • Manulik Ol'Ga Sergeevna
  • Negrimovskij Vladimir Mikhajlovich
  • Flid Vitalij Rafailovich
  • Shamsiev Ravshan Sabitovich
  • Juzhakova Ol'Ga Alekseevna
  • Jashtulov Nikolaj Andreevich
RU2470030C1
METHOD OF REFINING OIL, GAS CONDENSATE AND OIL FRACTIONS FROM MERCAPTANS 2007
  • Tarkhanova Irina Gennadievna
  • Smirnov Vladimir Valentinovich
  • Gantman Mikhail Gennad'Evich
RU2358004C1
CATALYTIC COMPOSITION FOR DEMERCAPTANISATION OF OIL AND OIL PRODUCTS 2011
  • Sheljapin Oleg Pavlovich
  • Provorova Nadezhda Vital'Evna
  • Borovkov Aleksandr Grigor'Evich
  • Kultaev Valentin Nikolaevich
  • Mazgarov Akhmet Mazgarovich
  • Vil'Danov Azat Faridovich
  • Asljamov Il'Dar Ravilevich
  • Voronin Evgenij Konstantinovich
  • Akhtjamov Oskar Zufarovich
  • Shchelyvanov Evgenij Jur'Evich
RU2458968C1
CATALYTIC COMPOSITION FOR OIL AND GAS CONDENSATE DEMERCAPTANISATION 2016
  • Shelyapin Oleg Pavlovich
  • Mazgarov Akhmet Mazgarovich
  • Vildanov Azat Faridovich
  • Voronin Evgenij Konstantinovich
  • Akhtyamov Oskar Zufarovich
  • Borovkov Aleksandr Grigorevich
  • Kultaev Valentin Nikolaevich
  • Aslyamov Ildar Ravilevich
  • Korobkov Fedor Aleksandrovich
  • Shchelyvanov Evgenij Yurevich
RU2656100C2
METHOD OF PRODUCING NANOSTRUCTURED PHTHALOCYANINE CATALYST FOR DEMERCAPTANISATION OF OIL AND GAS CONDENSATE 2013
  • Sheljapin Oleg Pavlovich
  • Voronin Evgenij Konstantinovich
  • Voronin Aleksandr Evgen'Evich
  • Akhtjamov Oskar Zufarovich
  • Shchelyvanov Evgenij Jur'Evich
  • Mazgarov Akhmet Mazgarovich
  • Vil'Danov Azat Faridovich
  • Asljamov Il'Dar Ravilevich
  • Borovkov Aleksandr Grigor'Evich
  • Kultaev Aleksandr Valentinovich
RU2517188C1

RU 2 381 065 C1

Authors

Vorozhtsov Georgij Nikolaevich

Egorova Ol'Ga Jur'Evna

Kalija Oleg Leonidovich

Kravchuk Ol'Ga Vital'Evna

Luk'Janets Evgenij Antonovich

Negrimovskij Vladimir Mikhajlovich

Petrova Ekaterina Grigor'Evna

Solov'Eva Ljudmila Ivanovna

Juzhakova Ol'Ga Alekseevna

Dates

2010-02-10Published

2008-10-21Filed