FIELD: chemistry.
SUBSTANCE: invention relates to a cobalt complex with a modified phthalocyanine ligand which is covalently bonded with silica gel and has the following general formula: 
, where: R=Cl, NHAlk, NAlk2, n = 5-7, M = Co. Also disclosed is a method for valence isomerisation of quadricyclane in norbornadiene in the presence of the complex.
EFFECT: invention enables to obtain a cobalt complex with a modified phthalocyanine ligand, which can be used as a heterogeneous catalyst having high activity and high stability.
3 cl, 1 tbl, 29 ex
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