FIELD: chemistry.
SUBSTANCE: described is a cross linking system for cross linking perfluoro-elastomers hardened using a peroxide method and having improved thermal stability at high temperatures above 300°C and below 350°C, containing the following: bis-olefin as a cross linking agent with formula: where R1, R2, R3, R4, R5, R6, identical or different from each other, represent H or C1-C5alkyls; Z represents a straight or branched C1-C18 alkylene or cycloalkylene radical, optionally containing oxygen atoms, preferably at least partially fluorinated or (per)fluoropolyoxyalkylene radical; amount of bis-olefin, expressed as a percentage of total mass of the polymer, ranges from 0.6% to 1.8%; peroxides for peroxide hardening, capable of generating radicals when heated, in amount ranging from 0.2% to 1.3% of the weight of the polymer. Also described are perfluoro-elastomers which are hardened using a peroxide method with such a cross linking system, and industrial products made with hardened perfluoro-elastomers.
EFFECT: reduced expenses of making the product.
23 cl, 6 ex, 1 tbl
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Authors
Dates
2010-03-10—Published
2005-06-21—Filed