FIELD: chemistry.
SUBSTANCE: invention can be used to obtain organosilanes by reacting (haloorganyl)alkoxysilane with a sulphonating agent. The reagent is selected from hydroxysulphides of alkali metals, sulphides of alkali metals Me2S, polysulphides of alkali metals Me2Sg and any combinations, where Me denotes an alkali metal, NH4 or (alkali-earth metal)1/2, and g ranges from 1.5 to 8.0. The reaction is also optionally carried out with sulphur and/or H2S in alcohol. Me2S or Me2Sg contains more than 10 wt % water and the alkali metal hydrosulphide contains more than 3 wt % water.
EFFECT: invention enables use of water-containing sulphonating agents and shortening the reaction time for obtaining organosilanes.
8 cl, 21 ex
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Authors
Dates
2010-06-10—Published
2006-03-07—Filed