FIELD: chemistry.
SUBSTANCE: device for chromatographic separation of substances contains three chromatographic columns connected to each other by crossover channels fitted with switching elements and extra channels fitted with switching elements which are connected to a source of the separated medium, eluent stream and system of receivers for collecting fractions. A controlled flow divider, one or more detectors and an analytical column are fitted at the output of the chromatographic separation system. Also in order to increase output and efficiency of the device for chromatographic separation of substances dissolved in supercritical fluids, the receivers for collecting fractions are fitted with level sensors and their outputs are further fitted with pilot-controlled valves which prevent diffusion of collected substances between receivers. The device also has a collector with a receiver and a flow regulator for the stream of fluids evaporated when pressure falls below the critical value. The device also has a high-pressure pump whose output is also connected to the flow regulator with pressure sensors at the input and output and a flow sensor, which guide part of the stream of formed fluids through the pilot-controlled valve into one or more spherical reactors which have an outer insulating layer and outer and inner heat chambers connected to heat or cold sources, temperature sensors, and the other part of the stream is directed to the analytical column and reactor. The reactor is connected through the pilot-controlled valve to the spherical collector of fluid solutions which is similar to the reactor whose output is connected to liquid batch collection device.
EFFECT: more accurate batching and increased output and efficiency of the disclosed device.
1 dwg
