CATALYST FOR OXIDISING HYDROCARBONS IN OXYGEN-CONTAINING GAS (VERSIONS) AND PREPARATION METHOD THEREOF Russian patent published in 2010 - IPC B01J23/34 B01J21/06 B01J21/04 B01J29/70 B01J37/02 B01D53/72 

FIELD: chemistry.

SUBSTANCE: invention relates to catalytic chemistry, specifically to catalysts for oxidation of hydrocarbons in an oxygen-containing gas and methods of preparing said catalysts. The invention describes a catalyst for oxidising hydrocarbons, which contains an active component - manganese oxide and a support in form of granular zirconium oxide with the following content of components, wt %: manganese oxide (MnO₂) 5.0-20.0; zirconium oxide (ZrO₂) 80.0-95.0. Described also is a catalyst which contains manganese oxide and a granular support made from powdered aluminium oxide in a mixture with crystalline mesoporous aluminium silicate with molar ratio Si/Al equal to 10-60:1, with the following ratio of components, wt %: manganese oxide (MnO₂) 5.0-20.0; aluminium oxide (Al₂O₃) 40.0-85.0; crystalline mesoporous aluminium silicate (Al_xSi_yO_z, where x=0.017-0.1, y=1, z=2.026-2.15) 10.0-40.0. The invention describes a method of preparing catalysts (versions) described above, involving preparation of a support - zirconium oxide or granular mixture of powdered aluminium oxide and crystalline mesoporous aluminium silicate and depositing onto the support manganese oxide, obtained through calcination at 500-600°C of the support saturated with aqueous manganese hydroxide solution after drying in an a temperature interval from 60 to 110°C.

EFFECT: higher catalytic activity and life of the catalyst.

6 cl, 1 tbl, 6 ex