BIFUNCTIONAL CABALT-CONTAINING ZEOLITE CATALYST, PREPARATION METHOD THEREOF AND METHOD FOR SYNTHESIS OF AROMATIC HYDROCARBONS Russian patent published in 2010 - IPC C07C1/04 B01J21/06 B01J21/10 B01J23/75 B01J29/46 

Abstract RU 2407730 C2

FIELD: chemistry.

SUBSTANCE: bifunctional cobalt-containing zeolite catalyst for synthesis of aromatic hydrocarbons (mixture of benzene, toluene, xylols and ethyl benzene) from synthetic gas contains a structural promoter - magnesium (II) oxide and an energy promoter - titanium oxide or hafnium oxide, in which the zeolite component used is zeolite ZVM in Ga form with molar ratio SiO2/Al2O3=30, and ratio of components in pts. wt: cobalt 50-150, magnesium (II) oxide 2-8, hafnium oxide or titanium oxide 2-5, zeolite (Ga form) 100-300, a method of preparing said catalyst and a method for synthesis of aromatic hydrocarbons from synthetic gas using said catalyst. The catalyst is characterised by low formation carbon dioxide - main by-product whose output is over 100 g/m3, and optimum ratio of components reaches 50 g/m3. Disclosed catalyst is characterised by high stability and enables synthesis of aromatic hydrocarbons without loss of selectivity for desired synthesis products for a long period of time (over 30 hours).

EFFECT: possibility of selective synthesis of aromatic hydrocarbons with output of desired products.

8 cl, 15 ex, 1 tbl

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RU 2 407 730 C2

Authors

Krylova Alla Jur'Evna

Krylova Majja Valer'Evna

Kulikov Al'Bert Borisovich

Knjazeva Marija Igorevna

Dolinskij Sergej Ehrikovich

Dates

2010-12-27Published

2009-01-29Filed