FIELD: technological processes.
SUBSTANCE: invention relates to the C2-C12 aliphatic hydrocarbons, C1-C5 alcohols, their esters or their mixtures to each other conversion catalyst into the high-octane gasoline component or aromatic hydrocarbons concentrate with their contact with this catalyst under the following conditions: temperature of 200–650 °C, pressure of 0.1–6.0 MPa, the raw materials feed volumetric rate (in liquid) of 0.1–10.0 h-1, i.e., invention also relates to this catalyst using method. Catalyst contains the high-silica zeolite of penthasils group (ZSM-5 or ZSM-11) with the mol ration of SiO2/Al2O3 = 20–150 mol/mol and the sodium oxide residual content of not more than 0.4 wt.%, zinc oxide and/or gallium oxide, lanthanum oxide, may contain one or more of rare earth elements oxides (cerium (IV) and/or neodymium and/or praseodymium), and/or iron (III) oxide and/or magnesium oxide and/or calcium oxide and/or phosphorus pentoxide and/or boron oxide and/or platinum group metal (Pt, Pd) and/or cobalt oxide, contains binder (gamma – Al2O3, and/or silica, and/or synthetic aluminosilicate, and/or clay, and/or zirconia, etc.), strontium oxide, wherein its content in the catalyst composition makes from 0.01 to 3.0 wt.%, zeolite content makes from 20.0 to 90.0 wt.%, zinc oxide content makes from 0.1 to 6.0 wt.%, gallium oxide content makes from 0.1 to 3.0 wt.%, lanthanum oxide (La2O3) content makes from 0.1 to 5.0 wt.%, rare earth elements oxides content (CeO2, Nd2O3, Pr2O3) makes from 0.1 to 1.0 wt.%, the iron (III), magnesium, calcium, phosphorus, boron, cobalt oxides content makes from 0.1 to 3.0 wt.%, platinum group metals (Pt, Pd) content makes from 0.05 to 1.0 wt.%, the binder component content is the balance to 100 wt.%.
EFFECT: increase in the liquid C5+ hydrocarbons yield and increase in the aromatic hydrocarbons content in them.
5 cl, 4 tbl, 53 ex
Title | Year | Author | Number |
---|---|---|---|
CATALYST AND METHOD OF CONVERTING ALIPHATIC C2-C12-HYDROCARBONS INTO HIGH- OCTANE GASOLINE COMPONENT OR AROMATIC HYDROCARBON CONCENTRATE | 2000 |
|
RU2165293C1 |
CATALYST FOR CONVERSION OF ALIPHATIC C2-C12 HYDROCARBONS INTO HIGH- ANTIKNOCK GASOLINE COMPONENT OR CONCENTRATE OF AROMATIC HYDROCARBONS | 1999 |
|
RU2172212C1 |
ZEOLITE-CONTAINING CATALYST AND METHOD OF CONVERTING $$$-HYDROCARBONS INTO HIGH-ANTIKNOCK GASOLINE COMPONENT OR AROMATIC HYDROCARBON CONCENTRATE | 1996 |
|
RU2100075C1 |
CATALYST FOR CONVERTING ALIFATIC C-C-HYDROCARBONS AND CONVERSION OF THESE HYDROCARBONS | 1996 |
|
RU2087191C1 |
METHOD FOR PRODUCTION OF HIGH-OCTANE BENZENES AND AROMATIC HYDROCARBONS | 1996 |
|
RU2098455C1 |
CATALYST FOR CONVERTING ALIFATIC C-C-HYDROCARBONS INTO ANTIKNOCK GASOLINE COMPONENT ENRICHED WITH AROMATIC HYDROCARBONS | 1994 |
|
RU2092240C1 |
METHOD FOR PRODUCTION OF MIXTURE OF HYDROCARBONS $$$ | 1996 |
|
RU2100332C1 |
PLANT FOR PROCESSING ALIPHATIC HYDROCARBONS C-C USING ZEOLITE-CONTAINING CATALYSTS | 2017 |
|
RU2698302C1 |
COMPLEX INSTALLATION FOR PROCESSING MIXTURE OF HYDROCARBONS C-C OF VARIOUS COMPOSITION AND OXYGEN-CONTAINING COMPOUNDS | 2016 |
|
RU2671568C1 |
CATALYST AND METHOD FOR PREPARING LIQUID HYDROCARBONS FROM DIMETHYL ETHER | 1999 |
|
RU2160160C1 |
Authors
Dates
2018-06-25—Published
2017-01-13—Filed