METHOD FOR SYNTHESIS OF 2,3-DIALKYL(ARYL)MAGNESACYCLOPENT-2-ENES Russian patent published in 2011 - IPC C07F3/02 

Abstract RU 2409583 C2

FIELD: chemistry.

SUBSTANCE: method involves combined reaction of disubstituted acetylenes with ethylmagnesiumdibromide in the presence of a zirconocene dichloride catalyst at excess ethylene pressure of 0.025 MPa and room temperature in a mixture of solvents diethyl ether: tetrahydrofuran (1:1). Output of the end product is 68-89%.

EFFECT: high output of end product.

1 cl, 1 ex, 1 tbl

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RU 2 409 583 C2

Authors

Sultanov Rifkat Mukhat'Jarovich

Vasil'Ev Vladimir Vladislavovich

Dzhemilev Usein Memetovich

D'Jakonov Vladimir Anatol'Evich

Popod'Ko Natal'Ja Romanovna

Salmijarova Elena Saljaevna

Dates

2011-01-20Published

2009-01-26Filed