Show metadata Hide metadata

(19)

(11)

2 547 265

(13)

(51)

IPC

C07F3/02(2006-01-01)

(21) (22)

Application

2010130376/04, 2010-07-20

(24)

Start date

2010-07-20

(22)

Actual filing date

2010-07-20

(45)

Published

2015-04-10

(72)

Inventor

Sultanov Rifkat Mukhat'JarovichVasil'Ev Vladimir VladislavovichDzhemilev Usein MemetovichSharipov Gljus Ljabibovich

(73)

Holder

Uchrezhdenie Rossijskoj Akademii Nauk Institut Neftekhimii I Kataliza Ran

METHOD FOR COMBINED PRODUCTION OF 2,3-DIALKYLMAGNESACYCLOHEPT-2-ENES AND 4,5-DIALKYLMAGNESACYCLOHEPT-4-ENES Russian patent published in 2015 - IPC C07F3/02

Abstract RU 2547265 C2

FIELD: chemistry.

SUBSTANCE: invention relates to organometallic synthesis, specifically to a method for combined production of 2,3-dialkylmagnesacyclohept-2-enes of general formula (1), where R=C₂H₅, H-C₃H₇, _H-C₄H₉, and 4,5-dialkylmagnesacyclohept-4-enes of general formula . The method includes reacting 2,3-dialkylmagnesacyclohept-2-enes with ethylene in the presence of a catalyst - zirconocene dichloride Cp₂ZrCl₂ under excess ethylene pressure of 1.0-1.5 MPa with molar ratio of 2,3-dialkylmagnesacyclohept-2-ene:Cp₂ZrCl₂=10:(0.3-0.6). The method is carried out in a solvent mixture of diethyl ether and tetrahydrofuran, taken in volume ratio of 5:1, at temperature of about 20°C for 6-8 hours.

EFFECT: obtained compounds can be used as cocatalysts in oligomerisation and polymerisation of olefins, acetylene and dienes, and as initial reactants for synthesis of different bifunctional and heterocyclic compounds.

1 tbl, 1 ex

Similar patents RU2547265C2

Title	Year	Author	Number
METHOD OF PRODUCING 2,3,4,5-TETRAALKYLMAGNESACYCLOPENTA2,4-DIENES	2010	Sultanov Rifkat Mukhat'Jarovich Vasil'Ev Vladimir Vladislavovich Dzhemilev Usein Memetovich	RU2440354C1
METHOD FOR PREPARING 2,3-DIALKYL-5-ALKYLIDENEMAGNESACYCLOPENT-2-ENES	2005	Dzhemilev Usein Memetovich Ibragimov Askhat Gabdrakhmanovich D'Jakonov Vladimir Anatol'Evich Zinnurova Regina Adikovna Dzhemileva Galina Arkad'Evna Khalilov Leonard Mukhibovich	RU2291870C1
METHOD FOR PREPARING 2,3,4,5-TETRAALKYLMAGNESA-CYCLOPENTA-2,4-DIENES	2005	Dzhemilev Usein Memetovich Ibragimov Askhat Gabdrakhmanovich D'Jakonov Vladimir Anatol'Evich Zinnurova Regina Adikovna Dzhemileva Galina Arkad'Evna Khalilov Leonard Mukhibovich	RU2290406C1
METHOD FOR SYNTHESIS OF 2,4-DIPHENYLMAGNESACYCLOHEPTANE	2009	Sultanov Rifkat Mukhat'Jarovich Vasil'Ev Vladimir Vladislavovich Dzhemilev Usein Memetovich	RU2423367C2
METHOD FOR SYNTHESIS OF 3,4-DIALKYLMAGNESACYCLOPENTANES	2009	Sultanov Rifkat Mukhat'Jarovich Vasil'Ev Vladimir Vladislavovich Dzhemilev Usein Memetovich	RU2423364C2
2,3,4,5-TETRAALKYLMAGNESACYCLOPENTA-2,4-DIENE SYNTHESIS METHOD	2008	Sultanov Rifkat Mukhat'Jarovich Vasil'Ev Vladimir Vladislavovich Dzhemilev Usein Memetovich Sharipov Gljus Ljabibovich D'Jakonov Vladimir Anatol'Evich	RU2397174C2
METHOD FOR PREPARING 1-CHLORO-2,3,4,5-TETRAALKYLALUMINACYCLOPENTA-2,4-DIENES	2005	Dzhemilev Usein Memetovich Ibragimov Askhat Gabdrakhmanovich Khafizova Lejla Osmanovna Jakupova Lilija Rafikovna Popod'Ko Natal'Ja Romanovna Kovtunenko Irina Anatol'Evna	RU2283315C1
METHOD FOR SYNTHESIS OF 2,3,4-TRIALKYLMAGNESACYCLOPENT-2-ENES	2009	Sultanov Rifkat Mukhat'Jarovich Vasil'Ev Vladimir Vladislavovich Dzhemilev Usein Memetovich D'Jakonov Vladimir Anatol'Evich	RU2423365C2
METHOD FOR PREPARING 3,4-DIALKYL-2,5-BIS-(TRIMETHYLSILYL)-MAGNESA-CYCLOPENTA-2,4-DIENES	2005	Dzhemilev Usein Memetovich Ibragimov Askhat Gabdrakhmanovich D'Jakonov Vladimir Anatol'Evich Zinnurova Regina Adikovna Dzhemileva Galina Arkad'Evna Khalilov Leonard Mukhibovich	RU2290405C1
METHOD OF COMBINED PREPARATION OF 1-(DIALKYLAMINE)-2,3- DIALKYL(PHENYL)ALUMACYCLOPROPENES, 1-(DIALKYLAMINE)-2,3- DIALKYL(PHENYL)ALUMACYCLOPENT-2-ENES AND 1- (DIALKYLAMINE)-2,3,4,5-TETRAALKYLALUMACYCLOPENTADIENES	1999	Dzhemilev U.M. Ibragimov A.G. Ramazanov I.R. Luk'Janova M.P. Chegodaeva M.F. Sharipova A.Z.	RU2157374C1

RU 2 547 265 C2

Authors

Sultanov Rifkat Mukhat'Jarovich

Vasil'Ev Vladimir Vladislavovich

Dzhemilev Usein Memetovich

Sharipov Gljus Ljabibovich

Dates

2015-04-10—Published

2010-07-20—Filed