FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing a dialkyltin compound, involving: a reaction for redistribution of alkyl groups and/or a reaction for dealkylation of a composition of a deactivated form of a catalyst based on dialkyltin, which is formed during synthesis of an ester derivative using a dialkyltin-based catalyst. The dialkyltin-based catalyst is a compound of at least one type selected from a group comprising a dialkyltin compound of formula (1) and tetraalkyldistanoxane of formula (2): (1) (where each of R1 and R2 independently denote a straight or branched alkyl group containing 1-12 carbon atoms, each of X1 and X2 independently denotes a substitute of at least one type selected from a group comprising an alkoxy group, an acyloxy group and a halogen atom, a and b independently denote an integer from 0 to 2 and a+b=2, and c and d independently denote an integer from 0 to 2 and c+d=2; (2), (where each of R3, R4, R5 and R6 independently denote a straight or branched alkyl group containing 1-12 carbon atoms, each of X3 and X4 independently denote a substitute of at least one type selected from a group comprising an alkoxy group, an acyloxy group and a halogen atom, and e, f, g and h independently denote an integer from 0 to 2, e+f=2 and g+h=2). The ester derivative is a compound of at least one type selected from a group comprising a carboxylic ester, a carbamate and isocyanate.
EFFECT: method enables production of versions of dialkyltin alkoxide compounds in active form in form of dialkyltin alkoxide compounds.
37 cl, 34 ex, 7 dwg
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Authors
Dates
2011-03-20—Published
2007-10-03—Filed