FIELD: chemistry.
SUBSTANCE: invention relates to preparation of mixed titanium and silicon dioxide and titanium-containing zeolites. The method of producing pyrogenic powder of mixed titanium and silicon dioxide, having BET specific surface area of 200-400 m2/g, involves evaporation of 97.0±1.5 wt % silicon halide (in terms of SiO2) and 3.5±1.0 wt % titanium halide (in terms of TiO2). The vapours are fed into a mixing chamber. Hydrogen and primary air are separately fed into the mixing chamber. The mixture of vapours of silicon halide and titanium halide, hydrogen-containing combustible gas and primary air are burnt in a burner and the flame is directed into the reaction chamber. Further, secondary air is fed into the reaction chamber. The solid substance is then separated from the gaseous substances and freed from halogen-containing substances via treatment with water vapour at temperature 250-700°C. Described is a dispersion which contains this powder and versions of the method of preparing a titanium-containing zeolite based on the powder or dispersion.
EFFECT: invention shortens the duration of producing the zeolite.
13 cl, 1 tbl, 9 ex
Title | Year | Author | Number |
---|---|---|---|
MIXED SILICON AND TITANIUM OXIDE-CONTAINING DISPERSION FOR PRODUCING TITANIUM-CONTAINING ZEOLITES | 2007 |
|
RU2424978C2 |
PRODUCTION OF POWDER-LIKE POROUS CRYSTALLINE SILICATES OF METALS USING FLAME SPRAY PYROLYSIS | 2018 |
|
RU2804511C2 |
METHOD FOR PRODUCING POWDER-LIKE POROUS CRYSTALLINE METAL SILICATES USING FLAME SPRAY PYROLYSIS | 2019 |
|
RU2800856C2 |
CARBONYLATION CATALYST AND METHOD | 2014 |
|
RU2696266C2 |
TITANIUM-CONTAINING ZEOLITE, METHOD OF ITS PRODUCTION (Versions), METHOD OF EPOXIDATION OF OLEFINS AND DIQUATERNARY AMMONIUM COMPOUND FOR PRODUCTION OF TITANIUM-CONTAINING ZEOLITE | 1994 |
|
RU2140819C1 |
TITANIUM-CONTAINING ZEOLITE PRODUCTION METHOD | 2001 |
|
RU2256613C2 |
EXHAUST GAS TREATMENT CATALYST CHARACTERIZED BY SILICA-BASED SUPPORT | 2002 |
|
RU2301702C2 |
METHOD FOR OXIDATION OF HYDROCARBONS AND CATALYST FOR OXIDATION OF HYDROCARBONS | 1999 |
|
RU2232157C2 |
CARBONYLATION METHOD | 2014 |
|
RU2658820C2 |
POWDER-LIKE TITANIUM DIOXIDE OBTAINED BY FLAMEHYDROLYSIS | 2004 |
|
RU2344994C2 |
Authors
Dates
2011-03-27—Published
2007-03-12—Filed