FIELD: chemistry.
SUBSTANCE: disclosed is alkoxy-modified silsesquioxane, containing one or more compounds selected from alkoxy-modified silsesquioxanes having formula
and mixtures thereof, where w, x and y are molar ratios, y is not equal to zero, either w or x, but not both simultaneously, can be equal to zero and w+x+y=1.0; R1, R2 and R3 are identical or different and are selected from a group comprising (i) H or alkyl C1-C20 groups, (ii) cycloalkyl C3-C20 groups, (iii) alkylaryl C7-C20 groups and (iv) R5X, where X is selected from a group comprising CI, Br, SH, SaR6, NR6 2, OR6, CO2H, SCOR6, CO2R6, OH, olefins, epoxides, amine groups, vinyl groups, acrylates and methacrylates, where a = 1-8, R5 is selected from alkylene C1-C20 groups and cycloalkylene C3-C20 groups, and R4 and R6 are selected from alkyl C1-C5 groups, cycloalkyl C3-C20 groups and alkylaryl C7-C20 groups. The invention also discloses a method of producing said alkoxy-modified silsesquioxanes, a vulcanised rubber mixture containing said silsesquioxanes and a method of preparing said mixture, as well as a pneumatic tyre made from said vulcanised rubber mixture.
EFFECT: low release of volatile organic compounds when preparing and processing vulcanised rubber mixtures which are prepared using the disclosed alkoxy-modified silsesquioxane, improved rubber reinforcement, high degree of the polymer-filler interaction and low viscosity of the said vulcanised rubber mixture, which enables to make pneumatic tyres with improved operational properties.
80 cl, 4 dwg, 36 tbl, 26 ex
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Year |
Author |
Number |
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