FIELD: process engineering.
SUBSTANCE: invention relates to method of producing iridium from (trifluorophosphine) iridium hydride tetrakis and may be used for production of high-purity metal iridium powder. Proposed method comprises ammonolysis of volatile complex compound of (trifluorophosphine) iridium hydride tetrakis Hlr(PF3)4 with conversion into nonvolatile iridium metallamine by water solution of ammonium. Then, iridium metallamine is dissolved in concentrated hydrogen nitrate and solution is evaporated. Evaporation over, residue is decomposed to sponge-structure metal iridium. Now, the latter is triturated, reduced in hydrogen flow and purified to high-purity iridium.
EFFECT: high-purity iridium powder.
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Authors
Dates
2011-05-27—Published
2009-07-20—Filed