FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing a perfluoroalkyne compound comprising a step for adding Cl2, Br2 or l2 to a compound of formula (1) CH3C≡CR1 to obtain a compound of formula (2) CH3CX2CX2R1, a step for fluorinating the compound of formula (2) with fluorine gas to obtain a compound of formula (3) CF3CX2CX2R2, and a dehalogenation step - reaction of the compound of formula (3) with a metal or organometallic compound to obtain a perfluoroalkyne compound of formula (4) CF3C≡CR2. In the formulae given above, R1 is a methyl or ethyl group, X is O, Br or I, and R2 is a trifluoromethyl group or a pentafluoroethyl group.
EFFECT: high efficiency and high output of the end product using starting materials which are ecologically clean and industrially accessible.
3 cl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING FLUOROHALOGENATED ETHERS | 2006 |
|
RU2433992C2 |
METHOD OF PRODUCING FLUORO-HALOGENATED ETHERS | 2006 |
|
RU2425022C2 |
METHOD FOR PRODUCTION OF HALOGEN-CONTAINING POLYETHER | 1991 |
|
RU2073692C1 |
HALOGEN-CONTAINING POLYETHER | 1992 |
|
RU2107074C1 |
METHOD FOR PRODUCING HALOGENATED ALKENE COMPOUND AND FLUORINATED ALKYNE COMPOUND | 2020 |
|
RU2793785C2 |
METHOD FOR PRODUCING A PERFLUOROALKYNE COMPOUND | 2019 |
|
RU2780974C1 |
METHOD OF OBTAINING 4-AMINO-5-FLUORO-3-HALOGEN-6-(SUBSTITUTED)PICOLINATES | 2012 |
|
RU2542985C1 |
METHOD FOR PREPARING FLUOROALKANOL | 2001 |
|
RU2263101C2 |
METHOD FOR PRODUCTION OF FLUORINATED KETONE | 2001 |
|
RU2279422C2 |
METHOD FOR PRODUCING A PERFLUOROCYCLOALKENE COMPOUND | 2019 |
|
RU2779442C1 |
Authors
Dates
2011-06-27—Published
2007-03-30—Filed