FIELD: metallurgy.
SUBSTANCE: procedure for extraction of nickel from solutions and purification from impurities: Cr3+, Fe3+, Al3+, Cu2+, Zn2+, Co2+, Fe2+, Mn2+, Ca2+, Mg2+ consists in bringing pH of solutions to values 4.0-6.5, in sorption of nickel at pH=4.0-6.5 from solutions or pulps on sub-acid cationites, in desorption of nickel from saturated cationites with solution of sulphuric or hydrochloric acid with production of solution of nickel strippant. Before desorption saturated cationite is treated with solution of nickel purified from impurities, also with portion of solution of strippant with concentration of nickel higher, than its concentration in source solution or pulp coming to sorption at a value of pH less, than pH of solution or pulp in the process of sorption. Ratio of CNI:ΣCimpurity in solution of strippant changes from 7:1 to 500:1.
EFFECT: more deep purification of solution of nickel strippant from impurities.
4 tbl
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METHOD OF CLEANING WASTE WATER FROM HEAVY AND NONFERROUS METAL IONS AND APPARATUS FOR REALISING SAID METHOD | 2010 |
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RU2453502C2 |
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Authors
Dates
2011-10-10—Published
2010-03-30—Filed