METHOD OF PRODUCING 1-IODO-2-ALKYL-3-(TRIMETHYLSILYL)-1,3-BIS-(DIISOBUTYLALUMINIUM)PROPANES Russian patent published in 2011 - IPC C07F5/06 

Abstract RU 2434874 C2

FIELD: chemistry.

SUBSTANCE: invention relates to organic synthesis, specifically to a method of producing novel organoaluminium compounds: 1-iodo-2-alkyl-3-(trimethylsilyl)-1,3-bis-(diisobutylaluminium)propanes. The compounds can be used as components of catalyst systems in oligomerisation and polymerisation of olefin, diene and acetylene hydrocarbons, as well as in fine organic and organometallic synthesis. The method involves reacting 1-alkyl-2-(trimethylsilyl)acetylenes with triisobutylaluminium in the presence of diidomethane in an argon atmosphere at temperature 20°C and atmospheric pressure in dichloromethane for 5-7 hours.

EFFECT: improved method.

1 cl, 1 ex, 1 tbl

Similar patents RU2434874C2

Title Year Author Number
METHOD OF PRODUCING 1-ALKYL-2-(TRIMETHYLSILYL)-CYCLOPROPANES 2008
  • Dzhemilev Usein Memetovich
  • Ramazanov Il'Fir Rifovich
  • Dil'Mukhametova Ljajsan Kadyrovna
  • Jumagulova Alsu Vakil'Evna
  • Sharipova Al'Fija Zufarovna
  • Shajbakova Marija Gennad'Evna
  • Dodonova Nina Egorovna
  • Ibragimov Askhat Gabdrakhmanovich
  • Sadykov Rais Askhatovich
RU2440360C2
METHOD OF PRODUCING DIISOBUTYL(2-ALKYL-3-(TRIMETHYLSILYL)CYCLOPROPYL)ALANES 2008
  • Dzhemilev Usein Memetovich
  • Ramazanov Il'Fir Rifovich
  • Dil'Mukhametova Ljajsan Kadyrovna
  • Jumagulova Alsu Vakil'Evna
  • Sharipova Al'Fija Zufarovna
  • Dodonova Nina Egorovna
  • Ibragimov Askhat Gabdrakhmanovich
  • Sadykov Rais Askhatovich
RU2417227C2
METHOD OF PRODUCING DIISOBUTYL[(2-ISOBUTYL-1-ALKYLCYCLOPROPYL)ETHYL]ALANES 2008
  • Dzhemilev Usein Memetovich
  • Ramazanov Il'Fir Rifovich
  • Dil'Mukhametova Ljajsan Kadyrovna
  • Sharipova Al'Fija Zufarovna
  • Shajbakova Marija Gennad'Evna
  • Ibragimov Askhat Gabdrakhmanovich
RU2382044C2
METHOD OF PRODUCING DIETHYL[2-(1-ALKYLCYCLOPROPYL)-2-ALKYLBUTYL]-ALANES 2007
  • Dzhemilev Usein Memetovich
  • Ramazanov Il'Fir Rifovich
  • Dil'Mukhametova Ljajsan Kadyrovna
  • Sharipova Al'Fija Zufarovna
  • Dodonova Nina Egorovna
  • Ibragimov Askhat Gabdrakhmanovich
RU2373213C2
METHOD OF DIETHYL[(2-ALKYL-2-(1-PHENYLCYCLOPROPYL)BUTYL]ALANS PRODUCTION 2007
  • Dzhemilev Usein Memetovich
  • Ramazanov Il'Fir Rifovich
  • Dil'Mukhametova Ljajsan Kadyrovna
  • Sharipova Al'Fija Zufarovna
  • Dodonova Nina Egorovna
  • Ibragimov Askhat Gabdrakhmanovich
RU2342397C1
METHOD OF DIETHYL[(2-ETHYL-1,2-DIALKYLCYCLOPROPYL)ETHYL]ALANS PRODUCTION 2007
  • Dzhemilev Usein Memetovich
  • Ramazanov Il'Fir Rifovich
  • Dil'Mukhametova Ljajsan Kadyrovna
  • Sharipova Al'Fija Zufarovna
  • Ibragimov Askhat Gabdrakhmanovich
RU2342396C1
METHOD FOR PREPARING 1-CHLORO-2,3,4,5-TETRAALKYLALUMINACYCLOPENTA-2,4-DIENES 2005
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • Khafizova Lejla Osmanovna
  • Jakupova Lilija Rafikovna
  • Popod'Ko Natal'Ja Romanovna
  • Kovtunenko Irina Anatol'Evna
RU2283315C1
METHOD FOR PREPARING 1-CHLORO-3,4-DIALKYL-2,5-BIS-(TRIMETHYLSILYL)-ALUMINACYCLOPENTA-2,4-DIENES 2005
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • Khafizova Lejla Osmanovna
  • Jakupova Lilija Rafikovna
  • Dzhemileva Galina Arkad'Evna
  • Kunakova Rajkhana Valiullovna
RU2295528C1
METHOD OF PREPARING 1,2-BIS/(DIALKYLAMINE)ALUMA/CIS-1,2- DIPHENYL (ALKYL)ETHYLENES 1996
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Dudoladova L.G.
  • Sultanov R.M.
  • Khalilov L.M.
RU2155768C2
METHOD OF PREPARING 1,2-BIS(DIALKOXY)ALUMA]-CIS-1,2- DIPHENYL(ALKYL)ETHYLENES 1996
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Dudoladova L.G.
  • Sultanov R.M.
  • Kunakova R.V.
RU2156766C2

RU 2 434 874 C2

Authors

Dzhemilev Usein Memetovich

Ramazanov Il'Fir Rifovich

Dil'Mukhametova Ljajsan Kadyrovna

Jumagulova Alsu Vakil'Evna

Sharipova Al'Fija Zufarovna

Shajbakova Marija Gennad'Evna

Ibragimov Askhat Gabdrakhmanovich

Sadykov Rais Askhatovich

Dates

2011-11-27Published

2008-10-23Filed