FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing new organoaluminium compounds, and specifically to a method of producing diethyl-[2-(1-alkylcyclopropyl)-2-alkylbutyl]-alanes of general formula (1): 
, where R= n-C2H5, n-C3H7, n-C4H9 characterised by that, 1,2-dialkylacetylene is reacted with triethylaluminium Et3Al in the presence of diiodomethane CH2I2, taken in molar ratio 1,2-dialkylacetylene:Et3Al:CH2I2 = 10:(55-65):(35-45) in an argon atomosphere at temperature ranging from 20 to 22°C at normal pressure in dichloromethane for 45 to 75 minutes.
EFFECT: obtaining new compounds, which can be used as components of catalyst systems in oligo- and polymerisation processes of olefins, diene and acetylene hydrocarbons, as well as in fine organic and organometallic synthesis.
1 cl, 1 tbl, 9 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF DIETHYL[(2-ETHYL-1,2-DIALKYLCYCLOPROPYL)ETHYL]ALANS PRODUCTION | 2007 |
|
RU2342396C1 |
| METHOD OF PRODUCING DIISOBUTYL[(2-ISOBUTYL-1-ALKYLCYCLOPROPYL)ETHYL]ALANES | 2008 |
|
RU2382044C2 |
| METHOD OF DIETHYL[(2-ALKYL-2-(1-PHENYLCYCLOPROPYL)BUTYL]ALANS PRODUCTION | 2007 |
|
RU2342397C1 |
| METHOD OF PRODUCING DIISOBUTYL(2-ALKYL-3-(TRIMETHYLSILYL)CYCLOPROPYL)ALANES | 2008 |
|
RU2417227C2 |
| METHOD OF PRODUCING 1-ALKYL-2-(TRIMETHYLSILYL)-CYCLOPROPANES | 2008 |
|
RU2440360C2 |
| METHOD FOR PREPARING 2,6-DIETHYL-5,7-DIPHENYL-1,2,3,3a,4,6,8,8a-OCTAHYDROALUMACYCLOPENTADIENO[3,4-f]-ISOALUMAINDOLE | 2004 |
|
RU2280037C2 |
| METHOD OF PRODUCING 1-IODO-2-ALKYL-3-(TRIMETHYLSILYL)-1,3-BIS-(DIISOBUTYLALUMINIUM)PROPANES | 2008 |
|
RU2434874C2 |
| 2,3-DIALKYL-2-CYCLOOCTENE-1-ONE PREPARATION PROCESS | 2016 |
|
RU2664661C2 |
| METHOD OF JOINT RECOVERY OF 2,3-DIALKYL-2-CYCLOHEPTENE-1-ONES AND 2,3-DIALKYL-2-CYCLOHEPTENE-1,4-DIONES | 2015 |
|
RU2624904C2 |
| METHOD OF OBTAINING 10-ETHYL-11,12-DIALKYL-10-ALUMINABICYCLO [7,3,0]DODECA-8,11-DIENES | 2007 |
|
RU2348640C1 |
