FIELD: chemistry.
SUBSTANCE: in order to simplify the process of producing alkyl silanes and their further purification, synthesis of alkylchloro silanes is carried out in the medium of aromatic hydrocarbons in the presence of a catalyst - tetrakis(diethylamido)-phosphonium salts, more preferably bromides and chlorides, at temperature ranging from 20°C to 250°C. The activator is used in amount of 0.005-1 mol, more preferably 0.01-0.05 mol for each substituted halogen atom in the initial alkylchloro silane.
EFFECT: disclosed method enables to obtain the end product with high purity and high output.
3 cl, 1 tbl, 8 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PREPARING ALKYLSILANES | 1999 |
|
RU2155189C1 |
METHOD FOR PREPARING METHYLSILANES | 2004 |
|
RU2266293C1 |
METHOD OF PRODUCING SEVOFLURANE | 2012 |
|
RU2479566C1 |
COMPOSITION OF POLYMERISATION CATALYST, METHOD OF PRODUCING SYNTHETIC POLYISOPRENE AND SYNTHETIC POLYISOPRENE | 2013 |
|
RU2590155C2 |
METHOD FOR PREPARING TRIMETHYLSILANE | 2006 |
|
RU2313532C1 |
HEAXAFLUOROBUTADIENE PRODUCTION PROCESS | 2003 |
|
RU2272017C2 |
MULTICOMPONENT COPOLYMER, RUBBER MIXTURE AND TIRE | 2015 |
|
RU2647594C1 |
METHOD OF PRODUCING POLYMER COMPOSITION AND POLYMER COMPOSITION | 2013 |
|
RU2607813C2 |
ANTI-VIBRATION RUBBER COMPOSITION, CROSS-LINKED ANTI-VIBRATION COMPOSITION AND ANTI-VIBRATION RUBBER | 2013 |
|
RU2579577C2 |
METHOD OF PREPARING FLUORINE-CONTAINING COMPOUNDS | 1997 |
|
RU2175958C2 |
Authors
Dates
2011-12-20—Published
2010-05-18—Filed