METHOD OF HYDROGENATING OLEFINS AND OXYGEN-CONTAINING COMPOUNDS IN SYNTHETIC LIQUID HYDROCARBONS OBTAINED VIA FISCHER-TROPSCH METHOD AND CATALYST FOR REALISING SAID METHOD Russian patent published in 2012 - IPC C07C1/22 C07C5/02 C07C9/00 C10G49/06 C10G45/10 C10G45/40 C10G69/02 B01J32/00 B01J23/44 C10G2/00 

Abstract RU 2446136 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a catalyst for realising a method of hydrogenating olefins and oxygen-containing compounds in synthetic liquid hydrocarbons obtained via a Fischer-Tropsch method, containing a porous support made from γ-aluminium oxide on which a catalytically active palladium component is deposited, characterised by that pores in the support have effective radius of 4.0-10.0 nm, wherein content of foreign-metal impurities in the support is not more than 1500 ppm, and content of palladium in the catalyst is equal to 0.2-2.5 wt %. The invention also relates to a hydrogenation method using said catalyst.

EFFECT: invention enables to obtain saturated hydrocarbons from liquid Fischer-Tropsch synthesis products, which are a complex mixture of paraffin hydrocarbons with 5-32 carbon atoms, with ratio of normal paraffin hydrocarbons to isoparaffin hydrocarbons ranging from 1:1 to 7:1, containing up to 50% olefins and up to 5% oxygen-containing compounds.

2 cl, 1 tbl, 7 ex

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RU 2 446 136 C1

Authors

Loginova Anna Nikolaevna

Sviderskij Sergej Aleksandrovich

Lysenko Sergej Vasil'Evich

Fadeev Vadim Vladimirovich

Gerasimov Denis Nikolaevich

Krukovskij Il'Ja Mikhajlovich

Aksenov Mikhail Sergeevich

Dates

2012-03-27Published

2010-09-30Filed