METHOD OF PRODUCING SYNTHETIC AVIATION FUEL FROM HYDROCARBONS OBTAINED VIA FISCHER-TROPSCH METHOD AND CATALYST FOR REALISING SAID METHOD Russian patent published in 2013 - IPC C10G2/00 C10G69/00 B01J23/40 B01J21/04 B01J29/40 B01J29/85 

Abstract RU 2473664 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a method of producing synthetic aviation fuel from hydrocarbons obtained via Fischer-Tropsch method, involving separation from the synthesised liquid products of the 135-280°C fraction which is subsequently divided into two fractions 135-190°C and 190-280°C by rectification, after which the fraction with the lowest boiling point is subjected to aromatisation at temperature of 400-500°C, at hydrogen pressure of 1.8-2.5 MPa, with volume rate of feeding material of 1.5-2.0 h-1 and ratio of hydrogen to the material of 1100-1500:1 nl/l over an aluminium-platinum catalyst promoted with rhenium, which contains 0.28-0.32 wt % platinum and 0.28-0.52 wt % rhenium, applied on a γ-Al2O3 support, content of foreign-metal impurities of which is not more than 1500 ppm, and the fraction with the highest boiling point is successively subjected to hydroisomerisation at temperature of 200-400°C, at hydrogen pressure of 2.0-7.0 MPa, volume rate of feeding material of 0.2-2.5 h-1, at ratio of hydrogen to the material of 300-1500:1 nl/l over a catalyst containing a catalytically active component - platinum, which is applied on a zeolite-containing support and a binder, wherein content of platinum in the catalyst is in the range of 0.15-0.60 wt %, content of zeolite is equal to 5-60 wt %, which is selected from the group: ZSM-5, ZSM-23, p, SAPO-11 or SAPO-41, wherein the binder used is γ-Al2O3 in the remaining amount, and then subjected to hydrofinishing at temperature of 180-240°C, at hydrogen pressure of 2.0-4.0 MPa, volume rate of feeding material of 1.0-12.0 h-1, with ratio of hydrogen to the material of 300-500:1 nl/l over an aluminium-palladium catalyst containing 0.2-2.0 wt % palladium, on γ-aluminium oxide with average pore radius of 4.0-10.0 nm, content of foreign-metal impurities of which is not more than 1500 ppm, after which the fractions are mixed and stabilised.

EFFECT: high output of end products which are suitable for producing high-quality aviation fuel after mixing and stabilisation.

2 cl, 1 tbl, 30 ex

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RU 2 473 664 C1

Authors

Loginova Anna Nikolaevna

Sviderskij Sergej Aleksandrovich

Potapova Svetlana Nikolaevna

Fadeev Vadim Vladimirovich

Mikhajlova Janina Vladislavovna

Lysenko Sergej Vasil'Evich

Gerasimov Denis Nikolaevich

Krukovskij Il'Ja Mikhajlovich

Aksenov Mikhail Sergeevich

Dates

2013-01-27Published

2011-12-05Filed