FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing elastomers or elastomer compositions, a system for production thereof and an elastomer composition obtained using said method. The method involves polymerisation of one or more C4-C7 isoolefins in the presence of a diluent which contains one or more fluorohydrocarbons in a reactor operating under suspension polymerisation conditions; extracting the output product of the reactor which contains a polymer product, unreacted monomer and diluent from the reactor; heating the suspension to temperature higher than the temperature of the unstable suspension by a value ranging from 1°C to about 50°C; extrusion of the output product of the reactor to separate at least a portion of the diluent and unreacted monomer from the polymer product; and recirculating the separated diluent and unreacted monomer into the reactor.
EFFECT: improved process of separating suspensions when producing elastomers and compositions thereof by using diluents or mixtures of diluents.
22 cl, 1 tbl, 4 dwg
Title | Year | Author | Number |
---|---|---|---|
METHOD OF SEPARATING SUSPENSION COMPONENTS | 2004 |
|
RU2371449C2 |
METHOD FOR SEPARATION OF COMPONENTS IN AZEOTROPIC OR AZEOTROPE-LIKE MIXTURE, AZEOTROPIC AND AZEOTROPE-LIKE MIXTURES FOR SEPARATION, EXTRACTIVE DISTILLATION SYSTEM FOR SEPARATION OF AZEOTROPIC OR AZEOTROPE-LIKE MIXTURE | 2004 |
|
RU2396241C2 |
PHASE SEPARATION METHOD USING FLUOROHYDROCARBON | 2007 |
|
RU2435791C2 |
POLYMERISATION METHODS INVOLVING HYDROFLUOROCARBONS | 2004 |
|
RU2355710C2 |
HALOGENATION METHODS | 2005 |
|
RU2422466C2 |
METHOD FOR PRODUCING ISOOLEFIN POLYMERS USING TERTIARY ETHER | 2019 |
|
RU2808455C2 |
METHOD OF PREPARING HYDROCARBON RUBBER ADHESIVE USING FLUOROHYDROCARBON DILUENT | 2007 |
|
RU2445322C2 |
METHOD OF REDUCING DEPOSITS IN POLYMERISATION VESSELS | 2008 |
|
RU2470037C2 |
COPOLYMERS WITH NEW DISTRIBUTIONS OF SEQUENCIES | 2003 |
|
RU2349607C2 |
CROSS-OVER POLYMERS ESSENTIALLY LONG BRANCHING FREE | 2003 |
|
RU2344145C2 |
Authors
Dates
2012-06-27—Published
2008-03-19—Filed