DICYCLOPENTADIENE POLYMERISATION CATALYST AND PREPARATION METHOD THEREOF Russian patent published in 2012 - IPC B01J23/46 B01J31/18 B01J37/00 C08F4/80 C08F32/00 C08G61/08 C07F15/00 

Abstract RU 2462308 C1

FIELD: chemistry.

SUBSTANCE: invention relates to catalysis and preparation of dicyclopentadiene polymerisation catalysts. Described is a polymerisation catalyst having the formula: The structure of the catalyst employs a fundamentally new L substitute which gives the catalyst new properties. Described is a method of producing the catalyst by reacting a ruthenium triphenylphosphine complex with 1,1-diphenyl-2-propyn-1-ol in tetrahydrofuran or dioxane at boiling point of the solvent in an inert atmosphere, and then with tricyclohexylphosphine at room temperature in an inert atmosphere; the formed ruthenium indenylidene complex is separated and then successively reacted with 1,3-bis-(2,4,6-trimethylphenyl)-2-trichloromethylimidazolidine and the corresponding 2-vinylbenzylamine to form the end product.

EFFECT: high output of the catalyst and obtaining polydicyclopentadiene with improved application properties.

3 cl, 26 ex

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RU 2 462 308 C1

Authors

Bespalova Natal'Ja Borisovna

Cheredilin Dmitrij Nikolaevich

Afanas'Ev Vladimir Vladimirovich

Zemtsov Denis Borisovich

Dates

2012-09-27Published

2011-10-04Filed