FIELD: chemistry.
SUBSTANCE: invention relates to electrolytic methods of producing pure cerium hexaboride. The cerium source used is 1-4 wt % anhydrous cerium chloride, the boron source is 1-3 wt % potassium fluoroborate and the background electrolyte is a eutectic mixture of potassium, sodium and cerium chlorides, which makes up the balance amount. Synthesis of ultrafine cerium hexaboride powder takes place via electrolysis from a eutectic melt of KCl-NaCl-CsCl, which contains cerium chloride and potassium fluoroborate.
EFFECT: invention enables to obtain a pure end product owing to good solubility of the eutectic background electrolyte in water and reducing power consumption by reducing synthesis temperature.
2 cl
Title | Year | Author | Number |
---|---|---|---|
ELECTROLYTIC METHOD OF PRODUCING ULTRAFINE GADOLINIUM HEXABORIDE POWDER | 2012 |
|
RU2507314C1 |
ELECTROLYTIC METHOD OF OBTAINING NANOSIZED CERIUM HEXABORIDE POWDER | 2013 |
|
RU2540277C1 |
ELECTROLYTIC METHOD OF OBTAINING ULTRAFINE POWDER OF GADOLINIUM HEXABORIDE | 2011 |
|
RU2466217C1 |
ELECTROLYTIC METHOD FOR OBTAINING ULTRAFINE POWDER OF DYSPROSIUM HEXABORIDE | 2012 |
|
RU2510630C1 |
ELECTROLYTIC METHOD FOR OBTAINING ULTRADISPERSE POWDER OF LANTHANUM HEXABORIDE | 2011 |
|
RU2477340C2 |
ELECTROLYTIC METHOD OF OBTAINING NANOSIZED POWDER OF NEODYMIUM HEXOBORIDE | 2008 |
|
RU2389684C2 |
ELECTROLYTIC METHOD OF PRODUCING SUPERDISPERSED POWDER OF CERIUM AND COBALT BORIDE | 2018 |
|
RU2695346C1 |
ELECTROLYTIC METHOD FOR SYNTHESIS OF PRASEODYMIUM HEXABORIDE | 2008 |
|
RU2393115C2 |
METHOD OF PRODUCING NANODISPERSED YTTRIUM HEXABORIDE POWDER | 2009 |
|
RU2448044C2 |
ELECTROLYTIC METHOD OF OBTAINING NANOSIZED CERIUM DISILICIDE POWDER | 2013 |
|
RU2539523C1 |
Authors
Dates
2012-11-10—Published
2011-05-13—Filed