FIELD: chemistry.
SUBSTANCE: invention relates to a method of obtaining cationic palladium complexes. Described is a method of obtaining cationic palladium complexes of general formula [(acac)Pd(L)2]BF4 (where acac denotes acetylacetonate, L denotes secondary amines such as diethylamine, dibutyalamine, dioctylamine and morpholine) by reacting a palladium complex with a secondary amine (L) in the medium of an organic solvent at room temperature, wherein the starting complex is a palladium complex of formula [(acac)Pd(MeCN)2]BF4 (where MeCN denotes acetonitrile) in molar ratio L:Pd=2:1 and the process is carried out in dichloromethane as the organic solvent.
EFFECT: carrying a method of obtaining cationic complexes in a single step.
4 ex
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Authors
Dates
2012-11-10—Published
2011-06-24—Filed