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2 636 742

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IPC

C07F15/00(2006-01-01)

C07F5/02(2006-01-01)

B01J31/22(2006-01-01)

(21) (22)

Application

2017101939, 2017-01-20

(24)

Start date

2017-01-20

(22)

Actual filing date

2017-01-20

(45)

Published

2017-11-28

(72)

Inventor

Pakhomova Marina VladimirovnaSuslov Dmitrij SergeevichBykov Mikhail ValerevichTkach Vitalij Sergeevich

(73)

Holder

Federalnoe Gosudarstvennoe Byudzhetnoe Obrazovatelnoe Uchrezhdenie Vysshego Obrazovaniya Gosudarstvennyj Universitet" Vo

METHOD OF PRODUCING PALLADIUM CATION COMPLEXES WITH TERTIARY AMINES Russian patent published in 2017 - IPC C07F15/00 C07F5/02 B01J31/22

Abstract RU 2636742 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a method of producing cationic palladium complexes containing organic and organoelement ligands of the general formula [Pd(acac)(L)]A, wherein A is BF₄. The method involves reacting a palladium complex with electron-donor ligands in dichloromethane or acetonitrile at room temperature. As the initial palladium complex, a cationic complex of the formula [Pd(acac)(MeCN)₂]BF₄is used, where acac is acetylacetonate, MeCN is acetonitrile. Monodentate tertiary amines such as tribenzylamine, triethylamine, tributylamine, N,N-diethylamine-2,7-octadiene, pyridine are used as electron-donor ligands of L.

EFFECT: invention makes it possible to produce cationic palladium complexes that can be used as components of catalytic systems.

5 ex

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RU 2 636 742 C1

Authors

Pakhomova Marina Vladimirovna

Suslov Dmitrij Sergeevich

Bykov Mikhail Valerevich

Tkach Vitalij Sergeevich

Dates

2017-11-28—Published

2017-01-20—Filed