METHOD OF PRODUCING CATIONIC COMPLEXES OF PALLADIUM WITH DIIMINE LIGANDS Russian patent published in 2013 - IPC C07F15/00 

Abstract RU 2475491 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a method of producing cationic complexes of palladium of general formula [(acac)Pd(L)]BF4, where acac denotes acetylacetonate, L denotes diimine ligands such as N,N'-bis(2,6-diisopropylphenyl)-2,3-butanediimine and N,N'-bis(2,6-dimethylphenyl)-2,3-butanediimine. The method involves reaction of a palladium complex with a ligand L in the medium of an organic solvent at room temperature in molar ratio L:Pd=1-1.33. The starting complex used is a palladium complex of formula [(acac)Pd(MeCN)2]BF4 (where MeCN denotes acetonitrile), and the organic solvent used is dichloromethane.

EFFECT: invention enables to obtain cationic complexes of palladium of the given formula in a single step.

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RU 2 475 491 C1

Authors

Suslov Dmitrij Sergeevich

Tkach Vitalij Sergeevich

Bykov Mikhail Valer'Evich

Belova Marina Vladimirovna

Mis'Ko Ol'Ga Ivanovna

Dates

2013-02-20Published

2011-11-21Filed