FIELD: chemistry.
SUBSTANCE: catalyst contains an organic compound of formula 1, an organometallic compound of formula 2, an organic transition metal compound of formula 3 and aluminoxane. Formula 1: R1-H or R1-Q-R1, where R1 is a cyclic hydrocarbyl group containing 5-30 carbon atoms and at least 2 conjugated double bonds, and can be unsubstituted or can contain 1-6 substitutes which are selected from alkyl groups containing 1-20 carbon atoms; Q is a divalent group for bridging groups R1, which is a (CR5 2)b group, where the substitute R5 is a hydrogen atom, b is an integer from 1 to 4. Formula 2: M1R2 mR3 nR4 pR6 q, where M1 is an element selected from a group consisting of group 1 and 2 elements, R2, R3, R4 and R6 independently denote a hydrocarbyl group containing 1-24 carbon atoms, m, n, p and q are independently equal to 0 or 1, and the sum m+n+p+q is equal to the valence of M1. Formula 3: M2R7 rXs, where M2 is titanium (Ti), zirconium (Zr) or hafnium (Hf), R7 is as defined for R1, X is a halogen atom, r is equal to 0 or 1, s is equal to 3 or 4, and the sum r+s is equal to the valence of metal M2. A method for polymerising olefin is also provided.
EFFECT: invention enables to obtain a catalyst having various catalytic properties in accordance with the combination of its components, and which can easily adjust molecular weight, molecular-weight distribution and composition of the obtained olefin polymer or copolymer.
8 cl, 10 ex
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Authors
Dates
2012-12-10—Published
2009-06-23—Filed