FIELD: polymerization catalysts. SUBSTANCE: invention relates to component of supported phosphinimine-cyclopentadienyl catalyst used in polymerization of olefins. Catalyst component contains (i) organometallic complex consisting of titanium, haffnium, and chromium; cyclopentadienyl ligand; phosphinimine ligand; two monovalent ligands; and (ii) granulated support. Catalyst, in particular. is used in polymerization of ethylene with at least one additional alpha-olefin. EFFECT: enhanced catalytic efficiency. 19 cl, 2 tbl, 21 ex
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Authors
Dates
2003-05-10—Published
1998-07-08—Filed