FIELD: polymerization catalysts. SUBSTANCE: invention provides new catalyst-on- carrier component containing (i) carrier material consisting of silica and alumoxane or trihydrocarbylaluminum compound with general formula A1R1
x
, in which each R1, independently from each other, is C2-C20-hydrocarbyl radical and x = 3, and (ii) activating compound including Broenstead acid cation capable of interacting with transition metal metallocene compound to form transition metal complex, which is catalytically active for polymerization of olefins, and a compatible anion with up to 100 nonhydrogen atoms containing at least one substituent including group with active hydrogen and depicted by general formula , wherein M' is boron, Q, independently in each case, is substituted C1-C20-hydrocarbyl, G is (r+1)-valent hydrocarbon radical linked to M', T is oxygen atom, m integer from 1 to 7, and n integer from 0 to 7. EFFECT: increased catalytic activity. 17 cl, 1 tbl, 29 ex
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Year |
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GAS-PHASE OLEFIN POLYMERIZATION (VERSIONS) |
1994 |
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METAL CHELATES COMPRISING LIGANDS OF 3-ARYL-SUBSTITUTED INDENYL, CATALYST OF OLEFIN POLYMERIZATION AND METHOD OF POLYMERIZATION |
1997 |
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1997 |
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COMPLEX BICYCLOPENTADIENYLDIENE COMPOUNDS AND METHOD OF POLYMERIZATION OF OLEFINS |
1995 |
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SUPPORTED CATALYST CONTAINING CATION-FORMING BOUND ACTIVATOR |
1996 |
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CARRIER-BASED CATALYST COMPONENT, METHOD OF PREPARING THEREOF, AND POLYADDITION METHOD |
1995 |
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TITANIUM(II) AND ZIRCONIUM(II) COMPLEXES, CATALYTIC COMPOSITION, AND METHOD OF POLYMERIZATION OF ETHYLENICALLY UNSATURATED OLEFINS |
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METHOD OF PREPARING OF CATALYST USED FOR ALPHA-OLEFINS POLYMERIZATION, A COMPOSITION FOR PREPARING OF ALPHA-OLEFINS POLYMERIZATION CATALYST, AND A METHOD OF POLYOLEFINS SYNTHESIS |
1991 |
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METHOD OF SYNTHESIS OF POLYMERS AND MIXING COMPOSITIONS CONTAINING THEREOF |
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SUBSTITUTED MONOCYCLOPENTADIENYL METALLIC COMPLEX, METHOD OF PREPARATION THEREOF, AND METHOD OF PREPARING ETHYLENE (CO)POLYMERS |
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