FIELD: chemistry.
SUBSTANCE: invention relates to a bridge metallocene of general formula 1 where M1 is a group IVb metal, values of radicals R1, R2, R3, R4, R4, R10, R11, R11 and R300 are as indicated in the claim. Methods of polymerising olefins are also provided.
EFFECT: bridge metallocenes are used as polymerisation catalyst components and demonstrate higher efficiency, molecular weight of the olefin polymer and low melt flow rate.
66 cl, 1 dwg, 12 tbl, 24 ex
Title |
Year |
Author |
Number |
RACEMOSELECTIVE SYNTHESIS OF ANSA-METALLOCENE COMPOUNDS, ANSA-METALLOCENE COMPOUNDS, CATALYSTS CONTAINING SAID COMPOUNDS, METHOD OF PRODUCING OLEFIN POLYMER USING CATALYSTS AND OLEFIN HOMO- AND COPOLYMERS |
2007 |
- Shul'Te Jorg
- Zell' Torsten
- Torn Mehtt'Ju Grant
- Vinter Andreas
- Dimeska Anita
|
RU2476449C2 |
METALLOCENE CATALYSTS, THEIR SYNTHESIS AND THEIR APPLICATION FOR OLEFIN POLYMERISATION |
2005 |
- Pachkovski Nikola
- Vinter Andreas
- Langkhauzer Frants
|
RU2360931C2 |
METHOD OF OBTAINING METALLOCENE HALOGENIDE COMPOUNDS |
2004 |
- Gvidotti Simona
- Bal'Boni David
|
RU2335504C2 |
CATALYST SYSTEM FOR POLYMERIZATION OF OLEFINS, PREPARATION THEREOF, AND PROPYLENE POLYMERIZATION PROCESS |
1995 |
- Ehntoni Nikolas Speka
- Dzheffri Lorens Brinen
- Dzhordzh Allen Vogn
- Patrik Brant
- Terri Dzhon Burkkhardt
|
RU2153507C2 |
RACEMIC-SELECTIVE OBTAINING, YIELDING ANSA-METALLOCENE BIPHENOXIDE COMPLEXES, WITH RELATIVELY SHORT ISOMERISATION TIME |
2003 |
- Damrau Khans-Robert-Khell'Mut
- Mjuller Patrik
- Garsija Valeri
- Sido Kristian
- Tell'E Kristian
- Lelon Zhan-Fransua
|
RU2329272C2 |
ORGANOBORON COMPOUND, METHOD OF PREPARING THEREOF, CATALYST SYSTEM, METHOD OF PREPARING OLEFINIC POLYMER, AND POLYOLEFIN |
1997 |
- Kornelija Frittse
- Frank Kjuber
- Khans Bonen
|
RU2147585C1 |
RACEMOID SELECTIVE OBTAINING OF BRIDGE METALLOCENE COMPLEXES WITH UNSUBSTITUTED OR 2-SUBSTITUTED INDENYL LIGANDS |
2003 |
- Damrau Khans-Robert-Khel'Mut
- Mjuller Patrik
- Garsija Valeri
- Sido Kristian
- Tell'E Kristian
- Lelon Zhan-Fransua
- Jur'E Ehrik
|
RU2330040C2 |
METHOD OF TRANSITIONING BETWEEN INCOMPATIBLE OLEFIN POLYMERISATION CATALYST SYSTEMS |
2009 |
- Majer Gerkhardus
- Mikhan Shakhram
- Kovetstsi Massimo
|
RU2501813C2 |
METALLOCENE SUPPORTED CATALYTIC SYSTEMS FOR POLYMERIZATION OF OLEFINS, METHOD OF THEIR PRODUCTION, HOMOPOLYMERS OR COPOLYMERS OF PROPYLENE AND METHOD OF THEIR PRODUCTION |
1994 |
- Terri Dzhon Barkkhardt
- Dzheffri Lorens Brinen
- Gregori Dzhordzh Khlatki
- Val'Ter Shpalekk
- Andreas Vinter
|
RU2126017C1 |
METHOD OF TRANSITION BETWEEN NON-COMPATIBLE SYSTEMS OF OLEFIN POLYMERISATION CATALYSTS |
2009 |
- Majer Gerkhardus
- Mikhan Shakhram
|
RU2510703C2 |