FIELD: chemistry.
SUBSTANCE: invention claims improved method of obtaining metallocene halogenide compounds of the general formula (V) 
, where M is Zr, L is Cl, R1 is CH3, R4 is C1-C6 alkyl; R5, R6, R7, R8 and R9 are H, or C1-C20 alkyl, C7-C20 arylalkyl, or two vicinial R5, R6, R7, R8 and R9 form condensed 6-member unsaturated cycle, by the effect of halogenisation agent of the formula III, R3 xTLw, where L is Cl, T is Al, R3 is C1-20 alkyl, to a compound of the formula V, where L is substituted to L' , where L' is methyl.
EFFECT: high output and easy separation of racemic and meso-form due to high solubility of intermediate alkylated metallocene.
4 cl, 3 ex
| Title |
Year |
Author |
Number |
| POLYPROPYLENE COMPOSITION |
2004 |
- Berta Dominik A.
- Pellegatti Dzhampaolo
|
RU2365605C2 |
| ORGANOMETALLIC COMPOUND SUITABLE AS COCATALYST IN POLYMERIZATION OF OLEFINS |
2001 |
- Reskoni Luidzhi
- Gvidotti Simona
|
RU2248980C2 |
| METALLOCENE COMPOUND ISOMERISATION METHOD |
2004 |
- Gvidotti Simona
- Bal'Boni Davide
|
RU2351603C2 |
| METALLOCENE COMPOUND, LIGAND, METHODS FOR PREPARING LIGAND, CATALYST, METHOD FOR PREPARING ALPHA-OLEFINS POLYMER, PROPYLENE HOMOPOLYMER, PROPYLENE COPOLYMER |
2000 |
- Nifant'Ev I.E.
- Guidotti Simona
- Reskoni Luidzhi
- Lajshevtsev I.P.
|
RU2243229C2 |
| METHOD OF PREPARING METALOCENES HAVING BRIDGE BONDS |
1995 |
- Mikhaehl' Aul'Bakh
- Frank Kjuber
|
RU2161621C2 |
| ORGANOBORON COMPOUND, METHOD OF PREPARING THEREOF, CATALYST SYSTEM, METHOD OF PREPARING OLEFINIC POLYMER, AND POLYOLEFIN |
1997 |
- Kornelija Frittse
- Frank Kjuber
- Khans Bonen
|
RU2147585C1 |
| AMPHOTERIC TRANSITION METAL COMPOUNDS, METHOD OF PREPARING THEREOF, METHOD OF POLYMERIZATION OF OLEFINS, AND CATALYST COMPONENT FOR THIS METHOD |
1995 |
- Gerkhard Ehrker
- Bodo Temme
- Mikhaehl' Aulbakh
- Bernd Bakhmann
- Frank Kjuber
|
RU2140922C1 |
| METHOD OF SYNTHESIS OF BRIDGE METALLOCENE COMPOUND, BRIDGE BIS-CYCLOPENTADIENYL LIGAND |
1996 |
- Nifant'Ev I.Eh.
- Ivchenko P.V.
- Reskoni Luidzhi(It)
|
RU2168515C2 |
| METALLOCENE COMPOUNDS, METHOD FOR THEIR PREPARING, CATALYST FOR POLYMERIZATION OF OLEFINS, METHOD FOR POLYMERIZATION |
2000 |
- Juehn Dzhon A.
- Ehlder Majkl Dzh.
- Dzhounz Robert L.
|
RU2245341C2 |
| METALLOCENE SUPPORTED CATALYTIC SYSTEMS FOR POLYMERIZATION OF OLEFINS, METHOD OF THEIR PRODUCTION, HOMOPOLYMERS OR COPOLYMERS OF PROPYLENE AND METHOD OF THEIR PRODUCTION |
1994 |
- Terri Dzhon Barkkhardt
- Dzheffri Lorens Brinen
- Gregori Dzhordzh Khlatki
- Val'Ter Shpalekk
- Andreas Vinter
|
RU2126017C1 |
