FIELD: chemistry.
SUBSTANCE: invention relates to the technology of polymers with a spatial-globular structure. The method of producing a polymer with a spatial-globular structure involves preparation of 30-60 vol. % monomer solution in an organic solvent, pouring said solution into a moulding means, curing in a polymerisation chamber either under the effect of ionising radiation for 10-80 s or in the presence of a polymerisation catalyst with UV radiation for 10-70 s or also in the presence of a polymerisation catalyst, heating to temperature 30-50°C and ageing for 10-80 s; the obtained polymer is washed in a water-alcohol bath and dried at 70-100°C, wherein the monomer used is dimethacrylate oligocarbonate; the organic solvent is selected from: primary alcohols - methyl alcohol, ethyl alcohol, isopropyl alcohol; amines are selected from diethylamine, triethylamine; carboxylic acid are selected from formic acid, acetic acid; carboxylic acid amides are selected from dimethyl formamide, dimethyl acetamide; ethyl acetate; and the polymerisation catalyst used is either peroxide compounds or azoisobutyronitrile or transition metal complexes or organometallic compounds of transition metals or salts of transition metals with variable oxidation states.
EFFECT: invention enables to obtain a polymer with a spatial-globular structure with given properties.
8 cl, 7 dwg, 2 tbl, 3 ex
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Authors
Dates
2012-12-27—Published
2011-07-07—Filed