FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing butanediol dimethacrylates, involving transesterification of an ester of methacrylic acid with butanediol, formed by an alcohol, containing 1-4 carbon atoms, in the presence of a catalyst, where the catalyst used is a combination which contains at least one lithium compound and at least one calcium compound, wherein at least one of the lithium and/or calcium compounds is an oxide, hydroxide, alkoxide containing 1-4 carbon atoms, or a carboxylate containing 1-4 carbon atoms, and the reaction takes place in the presence of water in amount of 0.005-8 wt % with respect to the weight of the butanediol used at the beginning of the reaction, with optional ageing of said amount of water for the entire transesterification process.
EFFECT: method enables to obtain butanediol methacrylates at a very low cost and having very high purity.
35 cl, 6 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING ETHYLENE GLYCOL DIMETHACRYLATE | 2008 |
|
RU2476420C2 |
METHOD OF PRODUCING (METH)ACRYLATES OF TETRA- OR MORE POLYBASIC ALCOHOLS | 2006 |
|
RU2446144C2 |
METHOD OF CONTINUOUS PRODUCTION OF ALKYLAMINO(METH)ACRYLAMIDES | 2004 |
|
RU2374221C2 |
METHOD OF PRODUCING ALLYL METHACRYLATE | 2008 |
|
RU2486172C2 |
METHOD OF OBTAINING (MET)ACRYLIC ACID ETHERS | 2009 |
|
RU2515985C2 |
METHOD FOR SYNTHESIS OF ALKYL(METH)ACRYLATES | 2006 |
|
RU2409552C2 |
METHOD OF OBTAINING METHACRYLATED BENZOPHENONES | 2009 |
|
RU2536471C2 |
METHOD OF PRODUCING ISOSORBIDE ETHOXYLATE DI(METH)ACRYLATE | 2016 |
|
RU2702013C2 |
METHOD FOR SYNTHESIS OF DIMETHYLAMINOALKYL(METH)ACRYLATES | 2018 |
|
RU2749072C1 |
IMPROVED METHOD FOR CONTINUOUS PRODUCTION OF ALKYL(METH)ACRYLATES WITH MULTIPLE RECYCLING OF CATALYST | 2003 |
|
RU2407733C2 |
Authors
Dates
2013-01-20—Published
2008-05-08—Filed