FIELD: chemistry.
SUBSTANCE: invention can be used in chemical industry. Method of obtaining basic zinc carbonates includes chemical conversion of coarse-dispersed zinc oxide in water solution of carbon dioxide and ammonia, further formation of target product, its filtration, drying, condensation and return of gaseous products to the stage of chemical conversion. Chemical conversion of zinc oxide into basic zinc carbonate is performed in ammonia-carbonate water solution in heterogenic conditions with molar ratio carbon dioxide:ammonia, equal 1:(5-9), temperature 15-50 °C and atmospheric pressure.
EFFECT: invention makes it possible to obtain amorphous sediments of pentazinc hexahydroxodicarbonate Zn5(CO3)2(OH)6 of stoichiometric composition with particle size, which does not exceed 50 nm, to simplify the process, reduce energy consumption and ecological load on the environment.
1 dwg, 3 tbl, 5 ex
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Authors
Dates
2013-08-20—Published
2012-03-15—Filed