FIELD: electricity.
SUBSTANCE: disclosed is a composite cathode material consisting of a mechanical mixture of nanocrystals of lithium-iron phosphate (LiFePO4) and a phosphate with a Nasicon structure, specifically: either a double phosphate of the composition LixM2(PO4)3, where: x=1 for M=Tilv, Zrlv; x=3 for M=InIII, CrIII, FeIII; or a composite phosphate of the composition Li1+yMIV 2-yMIII y(PO4)3, where: ; Mlv=TiIV Zrlv; MIII=InIII, CrIII, FeIII; wherein the mixture is coated with carbon, with the following ratios of components, wt %: lithium - iron phasphate 82÷98; phosphate with a Nasicon structure 1÷15; carbon 1-6, wherein the size of lithium-iron phosphate crystals ranges from 20 to 100 nm, the size of crystals of the phosphate with a Nasicon structure ranges from 20 to 200 nm, thickness of the carbon coating ranges from 1 to 5 nm.
EFFECT: composite material significantly increases concentration of defects on the phase boundary and increases ion conductivity thereof.
4 dwg, 1 tbl
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Authors
Dates
2013-09-10—Published
2012-09-11—Filed